Abstract
The results of computer-assisted molecular modeling showed that 2,6,8,12-tetraoxa-4,10(1,4)-dibenzena-1,7(2,7)-difluorenacyclododecaphane-19,79-dione is promising as a receptor for polar organic molecules. This compound was synthesized by the reaction of 1,4-bis(bromomethyl)benzene with 2,7-dihydroxyfluoren-9-one in DMF in the presence of anhydrous potassium carbonate under strong dilution. Crystalline complexes of the title compound with DMF and nitrobenzene were isolated and studied by X-ray diffraction. In both complexes the substrate is located in the ligand cavity.
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Original Russian Text © Yu.A. Simonov, T.Yu. Bogashchenko, V.N. Pastushok, M.M. Botoshanskii, M.S. Fonar’, A.Yu. Lyapunov, N.G. Luk’yanenko, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 7, pp. 1092–1098.
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Simonov, Y.A., Bogashchenko, T.Y., Pastushok, V.N. et al. 2,6,8,12-Tetraoxa-4,10(1,4)-dibenzena-1,7(2,7)-difluorenacyclododecaphane-19,79-dione—A new macrocyclic receptor for polar organic molecules. Russ J Org Chem 42, 1075–1082 (2006). https://doi.org/10.1134/S1070428006070268
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DOI: https://doi.org/10.1134/S1070428006070268