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Synthesis, Molecular and Crystal Structure of Ethyl 5-Cyano-2-(Dicyanomethyl)-2-Methyl-4-Oxo-6-Phenyl-3-Azabicyclo[3.1.0]Hexane-1-Carboxylate

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Abstract

As a result of triple condensation of malonodinitrile with benzaldehyde and ethyl 2-chloro-3-oxobutanoate a compound with 3-azabicyclo[3.1.0]hexane framework is formed whose crystal structure is determined by X-ray crystallography. In the crystal structure a layered character of the molecular packing is found. Molecules are linked in the layer by H bonds of N-H…O=C and C-H…O=C types and also a large number of atom-atom contacts whose energy corresponds to potential wells.

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Authors and Affiliations

  1. Baku State University, Baku, Republic of Azerbaijan

    A. I. Ismiyev, R. K. Askerov & A. M. Maharramov

  2. Vladimir State University, Vladimir, Russia

    K. A. Potekhin & A. V. Maleev

Authors
  1. A. I. Ismiyev
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  2. K. A. Potekhin
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  3. A. V. Maleev
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  4. R. K. Askerov
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  5. A. M. Maharramov
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Correspondence to A. I. Ismiyev.

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Ismiyev, A.I., Potekhin, K.A., Maleev, A.V. et al. Synthesis, Molecular and Crystal Structure of Ethyl 5-Cyano-2-(Dicyanomethyl)-2-Methyl-4-Oxo-6-Phenyl-3-Azabicyclo[3.1.0]Hexane-1-Carboxylate. J Struct Chem 60, 485–493 (2019). https://doi.org/10.1134/S0022476619030181

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  • DOI: https://doi.org/10.1134/S0022476619030181

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