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Preparation and Properties of Dialdehyddextran

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The homophase oxidation of dextran with sodium metaperiodate in an aqueous solution was studied, and samples of dialdehyde dextran with a degree of substitution of 0.12–1.24 were prepared. The effect of reaction temperature, oxidizing agent concentration, and pH of the reaction medium on the ratio of oxidized units of different chemical composition, molecular weight characteristics of the reaction products, and solubility of dialdehyde dextran samples was studied. The degradation rate of dialdehyde dextran in solutions at various pH values was estimated and it was shown that the hydrolysis rate in solutions with pH 2.0 enhances with increasing the number of aldehyde groups in the samples of oxidized dextran. In a solution with pH 3.5, the lowest degree of hydrolysis of dialdehyde dextran samples is detected, which does not depend on the content of aldehyde groups in their composition.

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Funding

The work was carried out within the framework of task 2.2.02.01 of the State Research Programs “Chemical processes, reagents and technologies, bioregulators and bioorgchemistry,” 2021–2025.

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Authors and Affiliations

  1. Research Institute of Physical and Chemical Problems, Belarusian State University, 220030, Minsk, Belarus

    T. L. Yurkshtovich, Yu. I. Pristromova, N. V. Golub, S. O. Solomevich & R. I. Kosterova

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  1. T. L. Yurkshtovich
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  2. Yu. I. Pristromova
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  3. N. V. Golub
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  4. S. O. Solomevich
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  5. R. I. Kosterova
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Corresponding author

Correspondence to Yu. I. Pristromova.

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The authors declare no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, Nos. 11–12, pp. 1459–1467, August, 2022 https://doi.org/10.31857/S004446182211010X

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Yurkshtovich, T.L., Pristromova, Y.I., Golub, N.V. et al. Preparation and Properties of Dialdehyddextran. Russ J Appl Chem 95, 1800–1808 (2022). https://doi.org/10.1134/S1070427222120060

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  • DOI: https://doi.org/10.1134/S1070427222120060

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