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Hybrid Materials Based on Carbon Fabric Modified with Transition Metal Oxides and the Possibility of Their Use as Electrode Materials for Supercapacitors

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Abstract

The features of the formation of hybrid electrode materials based on carbon fabric modified with oxides of molybdenum, cobalt, nickel, iron, and tungsten upon polarization by an alternating asymmetric current are studied. It is shown that the fabricated hybrid materials are multiphase systems, the morphology of their surface is characterized by a fragmentary structure. A study of the electrochemical behavior of the produced hybrid materials was condicted during their cycling in an alkaline electrolyte. The calculated specific capacity ​​were 472, 1018, 1496, 1990 mF cm–2 at current densities of 30, 12, 6, 3 mA cm–2, respectively. The resulting hybrid electrode materials retain their specific capacity up to 77% after 1000 charge/discharge cycles, which suggests the possibility of their use in symmetrical supercapacitors with an alkaline electrolyte.

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Funding

This work was supported by the grant of the President of the Russian Federation SP-3068.2021.1.

The work was supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 121031700314-5.

Determination of the specific surface area of hybrid electrode materials was performed using the equipment of the Center for Collective Use. D. I. Mendeleev under the government assignment 13 TsKP.21.0009.

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Authors and Affiliations

  1. Platov South-Russian State Polytechnic University, 346428, Novocherkassk, Russia

    A. V. Khramenkova, A. I. Izvarin, O. A. Finaeva & V. V. Moshchenko

  2. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    K. M. Popov

Authors
  1. A. V. Khramenkova
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  2. A. I. Izvarin
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  3. O. A. Finaeva
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  4. V. V. Moshchenko
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  5. K. M. Popov
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Contributions

A.V. Khramenkova: development of a method for the synthesis of hybrid materials based on transition metal oxides on the surface of a carbon fabric, the concept of the article, analysis of experimental data, writing the manuscript; A.I. Izvarin: synthesis of hybrid materials; O.A. Finaeva: literature review; V.V. Moshchenko: study of the stability of hybrid electrode materials during long-term cycling; K.M. Popov: conducting electrochemical studies by the method of cyclic voltammetry.

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Correspondence to A. V. Khramenkova.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 4, pp. 509–516, March, 2022 https://doi.org/10.31857/S0044461822040120

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Khramenkova, A.V., Izvarin, A.I., Finaeva, O.A. et al. Hybrid Materials Based on Carbon Fabric Modified with Transition Metal Oxides and the Possibility of Their Use as Electrode Materials for Supercapacitors. Russ J Appl Chem 95, 568–574 (2022). https://doi.org/10.1134/S1070427222040139

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