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Preparation of Nanosized Particles of Cobalt in the Presence of Water-Soluble Polymers

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Abstract

The formation of cobalt particles in the presence of water-soluble polymers of various nature was studied. The use of polyethyleneimine made it possible to prepare a dispersion of cobalt particles with a narrow size distribution. The use of polystyrenesulfonic acid and poly-N-vinylpyrrolidone led to the formation of a dispersion of cobalt particles 1.8–35.0 nm in size. In the presence of polyacrylic acid, particles 3.5–19.5 nm in size are formed, which consist of cobalt oxide and metallic cobalt.

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Funding

The work was carried out as part of the implementation of the state problem of the Southern Scientific Center of the Russian Academy of Sciences for 2022

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Contributions

A.S. Ozerin synthesized a complex of polyethyleneimine with cobalt ions and prepared cobalt particles with the complex; A.E. Mikhailyuk prepared cobalt particles in the presence of polyacrylic acid and polystyrenesulfonic acid, studied solutions of mixtures of the obtained particles and polymers by spectrophotometry; F.S. Radchenko prepared cobalt particles in the presence of poly-N-vinylpyrrolidone, performed an analysis of the diffraction patterns of particle dispersions; I.A. Novakov set the research task.

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Correspondence to A. S. Ozerin.

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The authors declare no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 82–86, December, 2022 https://doi.org/10.31857/S0044461822010108

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Ozerin, A.S., Mikhailyuk, A.E., Radchenko, F.S. et al. Preparation of Nanosized Particles of Cobalt in the Presence of Water-Soluble Polymers. Russ J Appl Chem 95, 84–87 (2022). https://doi.org/10.1134/S1070427222010116

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  • DOI: https://doi.org/10.1134/S1070427222010116

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