Skip to main content
SpringerLink
Log in

Estimation of the Rate Constants of the Chemical Reaction Stages in a Enclosed Non-Isothermal Gradientless Reactor

  • Processes and Equipment of Chemical Industry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

A method is described to estimate the rate constants of the chemical reaction stages without using optimization algorithms. The idea of the method is to extend the proposed reaction mechanism by linearly dependent slow stages that do not affect the dynamics of the process. The efficiency of the method is illustrated by the reaction of olefin hydroalumination.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. Yagola, A.G., Yanfei, V., Stepanova, I.E., and Titarenko, V.N., Obratnye zadachi i metody ikh resheniya (Inverse problems and methods for their solution), Moscow: Binom. Laboratoriya Znanii, 2014.

    Google Scholar 

  2. Fedotov, V.Kh., Koltsov, N.I., Russ. J. Phys. Chem. B, 2016, vol. 10, no. 5, pp. 753–759. https://doi.org/10.1134/S1990793116050195

    Article  CAS  Google Scholar 

  3. Fedotov, V.Kh., Kol’tsov, N.I., Gaidai, N.A., Agafonov, Yu.A., Botavina, M.A., and Lapidus, A.L., Russ. J. Appl. Chem., 2016, vol. 89, no. 5, pp. 719–726. https://doi.org/10.1134/S1070427216050062

    Article  CAS  Google Scholar 

  4. Kol’tsov, N.I., Izv. Vuzov. Khimiya Khim. Tekhnologiya, 2018, vol. 61, no. 2, pp. 46–52. https://doi.org/10.6060/tcct.20186102.5584

    Article  CAS  Google Scholar 

  5. Fedotov, V.Kh., and Kol’tsov, N.I., Izv. Vuzov. Khimiya Khim. Tekhnologiya, 2018, vol. 61, no. 7, pp. 37–43. https://doi.org/10.6060/ivkkt.20186107.5714

    Article  CAS  Google Scholar 

  6. Kol’tsov, N. I., Russ. J. Appl. Chem., 2020, vol. 93, no. 10, pp. 1544–1552. https://doi.org/10.1134/S1070427220100092 

    Article  Google Scholar 

  7. Bykov, V.I. and Tsybenova, S.B., Nelineinye modeli khimicheskoi kinetiki (Nonlinear Models of Chemical Kinetics), Moscow: URSS, 2011.

    Google Scholar 

  8. Ismagilova, A.S. and Spivak, S.I., Obratnye zadachi khimicheskoi kinetiki (Inverse Problems of Chemical Kinetics), Saarbrucken: Lap Lambert Acad. Publ., 2013.

    Google Scholar 

  9. Parfenova, L.V., Vil’danova, R.F., Pechatkina, S.V., Khalilov, L.M., and Dzhemilev, U.M., J. Organomet. Chem., 2007, vol. 692, no. 16, pp. 3424–3429. https://doi.org/10.1016/j.jorganchem.2007.04.007

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The author is grateful for the discussion of the results of the work of Ph.D. V. Kh. Fedotov.

Author information

Authors and Affiliations

  1. Chuvash State University named after I. N. Ulyanova, 428015, Cheboksary, Russia

    N. I. Kol’tsov

Authors
  1. N. I. Kol’tsov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Kol’tsov.

Ethics declarations

The author declares that there is no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 3, pp. 296–300, January, 2021 https://doi.org/10.31857/S0044461821030026

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kol’tsov, N.I. Estimation of the Rate Constants of the Chemical Reaction Stages in a Enclosed Non-Isothermal Gradientless Reactor. Russ J Appl Chem 94, 284–288 (2021). https://doi.org/10.1134/S1070427221030022

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427221030022

Keywords:

Search

Navigation