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Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acceleration periods. This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system.

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Funding

The study was performed within the framework of the designing part of the government assignment no. 4.3230.2017/4.6 of the Ministry of Education and Science of the Russian Federation.

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Authors and Affiliations

  1. Volgograd State Technical University, Volgograd, 400005, Russia

    I. A. Novakov, M. A. Vaniev, S. V. Borisov, N. V. Sidorenko, A. B. Kochnov & G. D. Bakhtina

Authors
  1. I. A. Novakov
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  2. M. A. Vaniev
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  3. S. V. Borisov
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  4. N. V. Sidorenko
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  5. A. B. Kochnov
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  6. G. D. Bakhtina
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Corresponding author

Correspondence to S. V. Borisov.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 6, pp. 758–766.

Conflict of Interest

The authors declare that they have no conflict of interest.

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Novakov, I.A., Vaniev, M.A., Borisov, S.V. et al. Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral. Russ J Appl Chem 92, 787–795 (2019). https://doi.org/10.1134/S1070427219060089

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  • DOI: https://doi.org/10.1134/S1070427219060089

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