Abstract
The effect of direct gas fluorination on the surface properties of a nonwoven polypropylene material was studied. Direct gas fluorination with mixtures of different compositions allows directional variation of the surface properties of the nonwoven polypropylene material. The surface becomes more hydrophobic when using a mixture of fluorine and nitrogen but less hydrophobic when using a mixture of fluorine, oxygen, and nitrogen. The modification leads to changes in the chemical composition of the surface and in the roughness of the material. The nonwoven polypropylene materials thus obtained exhibit increased sorption capacity for spent oil or water, respectively. Variation of the properties of the nonwoven polypropylene material allows expansion of its applications.
Similar content being viewed by others
References
Aizenshtein, E.M., Tech. Textile, 2010, no. 23. http://www.rustm.net/catalog/article/1877.html. Cited March 13, 2019.
Kharitonov, A.P., Prog. Org. Coat., 2008, vol. 61, nos. 2–4, pp. 192–204.
Nazarov, V.G., Stolyarov, V.P., Baranov, V.A., and Evlampieva, L.A., Ross. Khim. Zh., 2008, vol. 52, no. 3, pp. 45–55.
Kharitonov, A.P., J. Fluorine Chem., 2000, vol. 103, pp. 123–127.
Friedrich, J., Vakuum Forsch. Praxis, 2002, vol. 14, no. 5, pp. 285–290.
Jagur-Grodzinski, J., Progr. Polym. Sci., 1992, vol. 17, pp. 361–415.
Prorokova, N.P., Istratkin, V.A., and Kharitonov, A.P., Dizain. Mater. Tekhnol., 2015, no. 5 (40), pp. 28–34.
Summ, B.D. and Goryunov, Yu.V., Fiziko-khimicheskie osnovy smachivaniya i rastekaniya (Physicochemical Principles of Wetting and Spreading), Moscow: Khimiya, 1976.
Esenkova, N.P., Mikhal’kova, A.I., and Bachernikova, S.G., Neft’ Gaz Prom-st., 2004, no. 3 (8), http://edinros.spb.ru/articles/3804. Cited March 13, 2019.
Schonhorn, H., Macromolecules, 1970, vol. 3, pp. 800–801.
Clark, D.T., Feast, W.J., Musgrave, W.K.R., and Ritchie, I., J. Polym. Sci., Part A: Polym. Chem., 1975, vol. 13, pp. 857–890.
Tressaud, A., Durand, E., Labrugère, C., Kharitonov, A.P., and Kharitonova, L.N., J. Fluorine Chem., 2007, vol. 128, pp. 378–391.
Prorokova, N.P., Istratkin, V.A., Kumeeva, T.Yu., Vavilova, S.Yu., Kharitonov, A.P., and Bouznik, V.M., RSC Adv., 2015, vol. 5, no. 55, pp. 44545–44549.
Kharitonov, A.P., Taege, R., Ferrier, G., and Piven, N.P., Surf. Coat. Int., Part B: Coat. Trans., 2005, vol. 88, no. 3, pp. 201–212.
Kharitonov, A.P., Moskvin, Y.L., and Kolpakov, G.A., Polym. Sci. USSR, 1985, vol. 27, no. 3, pp. 739–743.
Deryagin, B.V., Churaev, N.V., and Muller, V.M., Poverkhnostnye sily (Surface Forces), Moscow: Nauka, 1985.
Kumeeva, T.Yu., Prorokova, N.P., and Kichigina, G.A., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 4, pp. 579–586.
Kumeeva, T.Yu. and Prorokova, N.P., Russ. J. Phys. Chem. A, 2018, vol. 92, no. 2, pp. 346–351.
Kumeeva, T.Yu., Prorokova, N.P., Kholodkov, I.V., Prorokov, V.N., Buyanovskaya, A.G., Kabaeva, N.M., Gumileva, L.V., Barakovskaya, I.G., and Takazova, R.U., Russ. J. Appl. Chem., 2012, vol. 85, no. 1, pp. 144–149.
Boinovich, L.B. and Emelyanenko, A.M., Russ. Chem. Rev., 2008, vol. 77, no. 7, pp. 583–600.
Boinovich, L.B. and Emelyanenko, A.M., Langmuir, 2009. vol. 25, pp. 2907–2912.
Kosintsev, V.I., Bordunov, S.V., Pilepenko, V.G., Sechin, A.I., Kulikova, M.V., and Prokudin, I.A., Usp. Sovrem. Estestvozn., 2007, no. 8, pp. 84–86.
Acknowledgments
The authors are grateful to Dr. Sci. (Phys.-Math.) A.P. Kharitonov (Branch of the Institute of Energy Problems for Chemical Physics, Russian Academy of Sciences, Chernogolovka) for participating in implementation of the fluorination process, to Cand. Sci. (Eng.) V.A. Istratkin (Institute for Solution Chemistry, Russian Academy of Sciences) for participating in fluorination experiments, to Cand. Sci. (Eng.) A.I. Mikhal’kova (Research Institute of Nonwoven Materials, Serpukhov, Russia) for determining the sorption capacity, and to Cand. Sci. (Phys.-Math.) I.V. Kholodkov (Ivanovo State University of Chemical Technology, Ivanovo, Russia) for performing the atomic-force microscopic experiment. The study was performed using the equipment of the Center for Shared Use of Scientific Equipment “Upper Volga Regional Center for Physicochemical Research.”
Author information
Authors and Affiliations
Corresponding author
Additional information
Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 5, pp. 668–673.
Rights and permissions
About this article
Cite this article
Kumeeva, T.Y., Prorokova, N.P. Control of the Sorption Properties and Wettability of a Nonwoven Polypropylene Material by Direct Gas Fluorination. Russ J Appl Chem 92, 701–706 (2019). https://doi.org/10.1134/S1070427219050173
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427219050173