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Hydroprocessing of Vacuum Gas Oil on NiMo Sulfide Catalyst Supported on an Ordered Mesoporous Polymer

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Abstract

The MPF-NiMoS catalyst prepared in situ by decomposition of the thio salt [N(n-Bu)4]2[Ni(MoS4)2] in pores of an ordered mesoporous phenol-formaldehyde polymer was tested in hydroprocessing of vacuum gas oil in a batch reactor at 380–420°C and a pressure of 5.0 MPa for 5 h. The mean length of sulfide nanoparticles is 4.2 nm, and the mean number of layers is 2. The fraction of lighter products and the degree of desulfurization increase with temperature.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    E. A. Karakhanov, M. P. Boronoev, E. Yu. Dzhanaeva, I. I. Shakirov, M. V. Terenina & A. L. Maksimov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    A. L. Maksimov

Authors
  1. E. A. Karakhanov
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  2. M. P. Boronoev
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  3. E. Yu. Dzhanaeva
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  4. I. I. Shakirov
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  5. M. V. Terenina
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  6. A. L. Maksimov
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Correspondence to E. A. Karakhanov.

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Karakhanov, E.A., Boronoev, M.P., Dzhanaeva, E.Y. et al. Hydroprocessing of Vacuum Gas Oil on NiMo Sulfide Catalyst Supported on an Ordered Mesoporous Polymer. Russ J Appl Chem 92, 300–303 (2019). https://doi.org/10.1134/S1070427219020204

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  • DOI: https://doi.org/10.1134/S1070427219020204

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