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Friedel-Crafts Synthesis of New Porous Aromatic Frameworks for Stabilizing Gas Transport Properties of Highly Permeable Glassy Polymers

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Porous aromatic frameworks of new generation, PAF-FC, were prepared by the Friedel-Crafts reaction between tetraphenylmethane and dimethoxymethane and were characterized. The material obtained has the structure similar to that of PAF-11 and exhibits high porosity (SBET = 768 m2 g−1). Introduction of 10 wt % PAF-FC allows stabilization of the gas transport characteristics of poly[1-trimethylsilyl–1-propyne] (PTMSP) in time. For example, after 500-h annealing at 100°C, the CO2 permeability coefficient of the PTMSP/PAF-FC composite decreased by 15%, whereas the ideal CO2/N2 selectivity increased from 5.6 to 6.1. The resultant gas transport characteristics appeared to be comparable to those of the previously studied porous aromatic frameworks PAF-11. It should be noted that synthesis of PAF–11 requires using expensive chemicals in large amounts, whereas PAF-FC synthesis by linking of aromatic fragments of monomeric monomers using the Friedel-Crafts reaction is much simpler and involves the use of considerably less expensive chemicals.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    L. A. Kulikov, D. S. Bakhtin, V. G. Polevaya, A. V. Balynin, A. L. Maksimov & A. V. Volkov

  2. Moscow State University, Moscow, 119991, Russia

    L. A. Kulikov & A. L. Maksimov

Authors
  1. L. A. Kulikov
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  2. D. S. Bakhtin
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  3. V. G. Polevaya
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  4. A. V. Balynin
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  5. A. L. Maksimov
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  6. A. V. Volkov
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Correspondence to D. S. Bakhtin.

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Kulikov, L.A., Bakhtin, D.S., Polevaya, V.G. et al. Friedel-Crafts Synthesis of New Porous Aromatic Frameworks for Stabilizing Gas Transport Properties of Highly Permeable Glassy Polymers. Russ J Appl Chem 92, 199–207 (2019). https://doi.org/10.1134/S1070427219020058

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  • DOI: https://doi.org/10.1134/S1070427219020058

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