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Porous aromatic frameworks of co-cured diethynylbenzene (DEB) and vinyltrimethoxysilane (VTMS) with good thermo-oxidative stability

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Abstract

A series of new porous aromatic frameworks (PAA-VTMS) co-cured by diethynylbenzene (DEB) and vinyltrimethoxysilane (VTMS) have been described. Thermally treated PAA-VTMS were also investigated. When the ratio of DEB to VTMS was 1:1 (PAA-VTMS-4), it showed characteristic pores with uniform diameter, confirmed by scanning electron microscope (SEM) and transmission electron microscopy (TEM) analyses. The surface area of PAA-VTMS-4 was up to 457 m2/g and its pore size was 7 nm, related to the hyper-cross-linked structure with plentiful benzene units. The co-cured PAA-VTMS samples whose DEB/VTMS ratios were higher or less than 1:1 showed low surface area. CO2 uptake of PAA-VTMS-4 was 83 cm3/g at 0 °C and 72 cm3/g at 25 °C. The temperature of 5% weight loss of PAA-VTMS-4 was 388 °C in nitrogen and 346 °C in air. The surface area of the thermally treated sample (OPAA-VTMS-4) was decreased, but its CO2 uptake was as high as 115 cm3/g at 0 °C and 105 cm3/g at 25 °C. The OPAA-VTMS-4 sample almost did not decompose in N2, and the temperature of its 5% weight loss was 450 °C in air. It showed that PAA-VTMS with its new porous aromatic framework can be used at high temperature.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (contract Grant Number 51003030).

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Authors and Affiliations

  1. Shanghai Key Laboratory of Advanced Polymeric Materials, Department of Material Science and Technology, East China University of Science and Technology, Shanghai, 200237, China

    Xiaoxiao Yu, Ruobing Yu & Qianqian Li

  2. Department of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200436, China

    Zheng Jiao

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  1. Xiaoxiao Yu
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  2. Ruobing Yu
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Correspondence to Ruobing Yu.

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Yu, X., Yu, R., Li, Q. et al. Porous aromatic frameworks of co-cured diethynylbenzene (DEB) and vinyltrimethoxysilane (VTMS) with good thermo-oxidative stability. Iran Polym J 26, 413–421 (2017). https://doi.org/10.1007/s13726-017-0530-4

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