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Effect of Process Features and Parameters of Preparation of a Nickel Catalyst by Reduction of Nickel Nitrate with Hexamethylenetetramine on the Catalyst Performance in Synthesis of Nanofibrous Carbon

  • Catalysis
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Abstract

A promising method based on solution combustion was considered for preparing a catalyst for the synthesis of nanofibrous carbon and hydrogen. The temperature profile of the hexamethylenetetramine combustion front in the bulk of the catalyst precursor is presented on the basis of process imaging. Catalyst samples were tested in a quartz tubular reactor at a temperature of 550°С and a pressure of 1 atm with methane as reaction medium. The influence exerted by the procedure for introducing hexamethylenetetramine into the nitrate base of the catalyst on the performance of the catalyst precursor in synthesis of nanofibrous carbon was studied. The catalyst was obtained as solid foam-like agglomerate (mean size of NiO particles 13.8–35.2 nm).

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Authors and Affiliations

  1. Novosibirsk State Technical University, Novosibirsk, 630087, Russia

    P. B. Kurmashov, A. G. Bannov, M. V. Popov & A. A. Kazakova

  2. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630128, Russia

    A. V. Ukhina

  3. Sochi State University, Sochi, Krasnodar krai, 354000, Russia

    G. G. Kuvshinov

Authors
  1. P. B. Kurmashov
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  2. A. G. Bannov
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  3. M. V. Popov
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  4. A. A. Kazakova
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  5. A. V. Ukhina
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  6. G. G. Kuvshinov
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Correspondence to P. B. Kurmashov.

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Original Russian Text © P.B. Kurmashov, A.G. Bannov, M.V. Popov, A.A. Kazakova, A.V. Ukhina, G.G. Kuvshinov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 11, pp. 1649−1657.

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Kurmashov, P.B., Bannov, A.G., Popov, M.V. et al. Effect of Process Features and Parameters of Preparation of a Nickel Catalyst by Reduction of Nickel Nitrate with Hexamethylenetetramine on the Catalyst Performance in Synthesis of Nanofibrous Carbon. Russ J Appl Chem 91, 1874–1881 (2018). https://doi.org/10.1134/S1070427218110198

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  • DOI: https://doi.org/10.1134/S1070427218110198

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