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Mesoporous Zirconium Phosphonate Hybrid Bentonite as a Novel Efficient Catalyst for the Removal of Trace Olefins from Aromatics

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

A nove l mesoporous zirconium phosphonate hybrid bentonite (MZrPHB ) catalyst was prepared for the removal of trace olefins from refining aromat ic oil. Pyridine-FTIR, NH3‒TPD, XRD, and N2 adsorptiondesorption analysis were applied to characterize acidic properties and textural properties of catalysts. And its olefins removal performance of MZrPHB catalyst was evaluated in comparison with commercial clay catalyst. It is found that the MZrPHB catalyst possesses an abundance of weak Lewis acid centers, large surface area, and regular mesopore, and thus, exhibits a longer treat life and higher olefins conversion compared to commercial clay catalyst. MZrPHB prepared in this report can be considered as a promising and superior alternative material to commercial clays for the purification of aromatics.

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Authors and Affiliations

  1. Faculty of Chemical Engineering, Huaiyin Institute of Technology, Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province, 223003, Huai’an, China

    Mei Wu, Lingli Ni, Songlan Zhang, Shuang Li, Yuqi Wang, Jinlong Jiang & Jing Chen

  2. Huai’an Research Center of Chemical and Advanced Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Huai’an, 223005 Jiangsu, China

    Mei Wu

  3. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, 210009, Nanjing, China

    Yichang Pan

  4. Jiangsu Hanbon Sci. & Tech, Co., Ltd., Huai’an City, Jiangsu Province, China

    Haifeng Han

Authors
  1. Mei Wu
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  2. Haifeng Han
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  3. Lingli Ni
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  4. Songlan Zhang
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  5. Shuang Li
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  6. Yuqi Wang
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  7. Jinlong Jiang
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  8. Yichang Pan
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  9. Jing Chen
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Corresponding author

Correspondence to Mei Wu.

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The text was submitted by the authors in English.

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Wu, M., Han, H., Ni, L. et al. Mesoporous Zirconium Phosphonate Hybrid Bentonite as a Novel Efficient Catalyst for the Removal of Trace Olefins from Aromatics. Russ J Appl Chem 91, 758–763 (2018). https://doi.org/10.1134/S1070427218050051

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  • DOI: https://doi.org/10.1134/S1070427218050051

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