Skip to main content
SpringerLink
Log in

Effect of Cu Doping on the SCR Activity of Mn‒Ce/ATP Catalyst

  • Various Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

In this study, the Cu-doped Ce‒Mn/ATP denitration catalyst was prepared by impregnation method and heterogeneous precipitation method and its denitrification performance was tested. It was found that the denitrification effect was obviously improved after Cu doping. And the denitration effect of the catalyst prepared by the heterogeneous precipitation method was better and the denitrification rate was above 98%. Under this method, n(Cu: Mn) = 1 had the best denitration effect, with a maximum of 99.76%. The prepared catalysts were characterized by means of XRD, XPS, BET, and SEM. The results showed that CuMn2O4 and CuO appeared in the Cu doped catalysts. Moreover, the doping of Cu enriched the pore structure and surface morphology of the catalyst, so that the catalyst showed good denitrification performance.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yang, N. and Wang, X., Env. Protect. & Circ. Econ., 2010, vol. 11, pp. 63–67.

    Google Scholar 

  2. Shi, Y.L., Cui, S.H., Xu, S., et al., Acta Scientiae Circumstantiae, 2014, vol. 34,, no. 10, pp. 2684–2692.

    CAS  Google Scholar 

  3. Lu, Y., Cang, H., Han, F., et al., Asian J. Chem., 2012, vol. 24, no. 12, pp. 5759–5762.

    CAS  Google Scholar 

  4. Shen, B.X., Yao, Y., Ma, H.Q., and Liu, T., Chinese J. Catal., 2011, vol. 32:1803–1811.

    Article  CAS  Google Scholar 

  5. Khan, S.U.M., Al-Shahry, M., and Ingler, J.W.B., Science, 2002, vol. 29, no. 7, pp. 2243–2245.

    Article  Google Scholar 

  6. Park, K.H., Lee, S.M., Kim, S.S., et al., Catalysis Letters, 2013, vol. 143, no. 3, pp. 246–253.

    Article  CAS  Google Scholar 

  7. Choi, S.H., Cho, S.P., Lee, J.Y., et al., J. Mol. Catal., A: Chem., 2009, vol. 304, nos. 1–2, pp. 166–173.

    Article  CAS  Google Scholar 

  8. Lu, P., Li, C.T., Zeng, G.M., et al., Appl. Catal., B: Env., 2010, vol. 96, nos. 1–2, pp. 157–161.

    Article  CAS  Google Scholar 

  9. Gu, Y.J., Han, F.N., Tang, Z., et al., New Chem. Mat., 2015, vol. 43, no. 3, pp. 51–53.

    CAS  Google Scholar 

  10. Kang, M., Park, E.D., Kim, J.M., et al., Appl. Catal., A, 2007, vol. 327, no. 2, pp. 261–269.

    Article  CAS  Google Scholar 

  11. Guo, J., Li, C.T., Luo, P., et al., Env. Sci., 2011, vol. 32, no. 8, pp. 22402245.

    Google Scholar 

  12. Zhang, Y.P., Wang, X.L., Shun, K.Q., et al., J. Fuel Chem. & Technol., 2011, vol. 39, no. 10, pp. 782–786.

    CAS  Google Scholar 

  13. Zhang, L.F., Hefei University of Technology, 2014.

    Google Scholar 

  14. Min, Kang, Eun, Duck Park, Ji Man Kim, et al., Catalysis Today, 2006, 111, pp. 236–241.

    Article  Google Scholar 

  15. Wu, B., Huang, Y., Zheng, Y., et al., Acta Scientiae Circumstantiae, 2008, vol. 28, no. 5, pp. 960–964.

    CAS  Google Scholar 

  16. Chu, Y.H., Gai, Z.P., Wang, T.Z., et al, J. Sichuan Univ. (Eng. Sci. Ed.), 2015, vol. 47, no. 3, pp. 180–186.

    Google Scholar 

  17. Liu, W., Tong, Z.Q., Luo, J., et al., Acta Scientiae Circumstantiae, 2006, vol. 26, no. 8, pp. 1240–1245.

    CAS  Google Scholar 

  18. Tang, X.L., Hao, J.M., Xu, W.G., et al., Catal. Comm., 2007, vol. 8, no. 3, pp. 329–334.

    Article  CAS  Google Scholar 

  19. Liao, W.P., Yang, L., and Wang, F., et al., Acta Chimica Sinica, 2011, vol. 69, no. 22, pp. 2723–2728.

    CAS  Google Scholar 

  20. Huang, Y., Tong, Z., Wu, B., et al., J. Fuel Chem. Technol., 2008, vol. 36, no. 5, pp. 616–620.

    Article  CAS  Google Scholar 

  21. Song, L., Chen, T.H., Li, Y.X., et al., Chin. J. Catalysis, 2011, vol. 32, no. 4, pp. 652–656.

    CAS  Google Scholar 

  22. Li, F., Lei, T., Yang, Y., et al., J. Mat. Eng., 2015, vol. 43, no. 10, pp. 1–6.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Space and Environment, Beihang University, Beijing, 100083, China

    Naiye Qi & Xinghua Li

  2. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing, 100083, China

    Haijun Dan

Authors
  1. Naiye Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Haijun Dan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xinghua Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xinghua Li.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Qi, N., Dan, H. & Li, X. Effect of Cu Doping on the SCR Activity of Mn‒Ce/ATP Catalyst. Russ J Appl Chem 91, 136–142 (2018). https://doi.org/10.1134/S1070427218010214

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427218010214

Search

Navigation