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Structure and Thermal Stability of Nanostructured Precursor Powders of Copper(I) Sulfide and Selenide

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The hydrochemical precipitation method at 298 and 333 K with, respectively, thiocarbamide and sodium selenosulfate was used to obtain nanostructured powders of copper sulfide with formula composition Cu2S, which are composed of globules 200–500 nm in diameter, formed by 70–100-nm particles, and copper(I) selenide, composed of crystallites with polyhedral shape, sizes of 80 to 500 nm, and a formula composition Cu1.84Se. An X-ray diffraction analysis revealed the orthorhombic Cu2S structure (space group no. 39-Abm2) with unit cell parameters a = 1.182 nm, b = 2.705 nm, and c = 1.343 nm. Powders of Cu1.84Se copper selenide have a cubic structure (space group Fm3m) with lattice constant a = 0.5693 nm. A thermal analysis demonstrated that the chemically precipitated Cu2S and Cu1.84Se powders have a stable elemental composition up to 200–240°C. An intense oxidation of the samples begins at a temperature exceeding 250°C and is accompanied by a sharp decrease in their content of sulfur (selenium) and by an increase in the content of oxygen.

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Authors and Affiliations

  1. Ural Federal University Named after the First President of Russia B.N.Yeltsin, ul. Mira 19, Yekaterinburg, 620002, Russia

    L. N. Maskaeva, V. F. Markov, E. A. Fedorova & I. A. Berg

  2. Ural Institute of State Fire Service of EMERCOM of Russia, ul. Mira 22, Yekaterinburg, 620137, Russia

    L. N. Maskaeva & V. F. Markov

  3. The Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia

    R. F. Samigullina

  4. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620990, Russia

    V. I. Voronin

Authors
  1. L. N. Maskaeva
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  2. V. F. Markov
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  3. E. A. Fedorova
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  4. I. A. Berg
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  5. R. F. Samigullina
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  6. V. I. Voronin
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Correspondence to L. N. Maskaeva.

Additional information

Original Russian Text © L.N. Maskaeva, V.F. Markov, E.A. Fedorova, I.A. Berg, R.F. Samigullina, V.I. Voronin, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 10, pp. 1287−1294.

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Maskaeva, L.N., Markov, V.F., Fedorova, E.A. et al. Structure and Thermal Stability of Nanostructured Precursor Powders of Copper(I) Sulfide and Selenide. Russ J Appl Chem 90, 1572–1578 (2017). https://doi.org/10.1134/S1070427217100032

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  • DOI: https://doi.org/10.1134/S1070427217100032

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