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Influence of cerium oxide on properties of glass–ceramic sealants for solid oxide fuel cells

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Abstract

The influence of the cerium oxide concentration on the properties of glasses and glass ceramics of the SiO2–Al2O3–CaO–Na2O–MgO–K2O–B2O3–CeO2 system as potential adhesive and sealing materials for solid oxide fuel cells was studied. According to the data of differential scanning calorimetry, variation of the CeO2 concentration does not appreciably influence the glass transition and crystallization temperatures of glasses. As the cerium oxide concentration is increased, the linear thermal expansion coefficient increases for the glasses but decreases for the partially crystalline samples. The gluing temperature of the glass sealants prepared allows their use for joining YSZ solid electrolytes with interconnectors of Crofer22APU type in solid oxide fuel cells..

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    D. A. Krainova, S. T. Zharkinova, N. S. Saetova, A. A. Raskovalov, A. V. Kuz’min, V. A. Eremin, E. A. Sherstobitova & S. V. Pershina

  2. Yeltsin Ural Federal University, Yekaterinburg, Russia

    D. A. Krainova, A. V. Kuz’min & V. A. Eremin

  3. Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    E. A. Sherstobitova

  4. Belarussian State University of Technology, Minsk, Belarus

    M. V. Dyadenko

  5. Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, China

    Xiaoa Zhang & Shengling Jiang

Authors
  1. D. A. Krainova
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  2. S. T. Zharkinova
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  3. N. S. Saetova
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  4. A. A. Raskovalov
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  5. A. V. Kuz’min
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  6. V. A. Eremin
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  7. E. A. Sherstobitova
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  8. S. V. Pershina
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  9. M. V. Dyadenko
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  10. Xiaoa Zhang
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  11. Shengling Jiang
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Corresponding author

Correspondence to A. V. Kuz’min.

Additional information

Original Russian Text © D.A. Krainova, S.T. Zharkinova, N.S. Saetova, A.A. Raskovalov, A.V. Kuz’min, V.A. Eremin, E.A. Sherstobitova, S.V. Pershina, M.V. Dyadenko, Xiaoa Zhang, Shengling Jiang, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 1047−1053.

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Krainova, D.A., Zharkinova, S.T., Saetova, N.S. et al. Influence of cerium oxide on properties of glass–ceramic sealants for solid oxide fuel cells. Russ J Appl Chem 90, 1278–1284 (2017). https://doi.org/10.1134/S1070427217080146

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  • DOI: https://doi.org/10.1134/S1070427217080146

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