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Synthesis of high surface area NiO nanoparticles through thermal decomposition of mixed ligand Ni(II) Complex, [Ni(binol)(bpy)]∙CH3OH

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Abstract

The present work focuses on the synthesis of high surface area NiO nanoparticles through thermal decomposition of [Ni(binol)(bpy)]∙CH3OH complex as a new precursor. [Ni(binol)(bpy)]∙CH3OH (where binol = racemic-1,1′-bi-2-naphtholate and bpy = 2,2′-bipyridine) was synthesized from reaction of NiCl2(bpy) with rac-Na2(binol). The complex was characterized by elemental analysis and spectroscopy techniques of IR, UV-Vis, mass, 1H and 13C NMR. The results revealed that [Ni(binol)(bpy)]∙CH3OH was a paramagnetic tetrahedral complex. The physicochemical properties of the nanoparticles were characterized by various analysis techniques such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and BET specific surface area. The used synthetic rout is facile and economic that makes it suitable for large scale production of pure nickel oxide nanoparticles.

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  1. Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), P. O. Box 33535-111, Tehran, Iran

    A. Salehirad

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Salehirad, A. Synthesis of high surface area NiO nanoparticles through thermal decomposition of mixed ligand Ni(II) Complex, [Ni(binol)(bpy)]∙CH3OH. Russ J Appl Chem 89, 63–69 (2016). https://doi.org/10.1134/S10704272160010109

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  • DOI: https://doi.org/10.1134/S10704272160010109

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