Skip to main content
SpringerLink
Log in

Nanoporous carbon prepared by thermochemical treatment of carbide with chlorine

  • Various Technologies
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The influence exerted by the chemical composition of B, Si, Ti, Zr, Hf, V, Nb, Ta, Mo, and Cr carbides and by the temperature of their chlorination on the ordering in the arrangement of carbon layers forming the structure of nanoporouos carbon was demonstrated. The pore structure characteristics of the materials were studied in relation to the composition of the starting carbides and to the chlorination conditions. The specific surface area of the carbon materials, as a rule, drastically decreases as the chlorination temperature is increased over 900–1000°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rychagov, A.Yu., Vol’fkovich, Yu.M., Vorotyntsev, M.A., et al., Elektrokhim. Energet., 2012, vol. 12, no. 4, pp. 167–180.

    CAS  Google Scholar 

  2. Chmiola, J., Yushin, G., Dash, R.K., et al., Electrochem. Solid State Lett., 2005, vol. 8, no. 7, pp. A357–A360.

    Article  CAS  Google Scholar 

  3. Dash, R., Chmiola, J., Yushin, G.. et al.. Carbon, 2006, vol. 44, pp. 2489–2497.

    Article  CAS  Google Scholar 

  4. Leisa, J., Arulepp, M., Kuuraa, A., et al., Carbon, 2006, vol. 44, no. 11, pp. 2122–2129.

    Article  CAS  Google Scholar 

  5. Fedorov, N.F., Ross. Khim. Zh., 1995, vol. 39, no. 6, pp. 73–83.

    CAS  Google Scholar 

  6. Nikitin, A. and Gogotsi, Y., in Encyclopedia of Nanoscience and Nanotechnology, 2003, vol. 7, pp. 553–574.

    Google Scholar 

  7. Smirnov, A.V., Fedorov, B.A., Petrov, N.A., et al., Dokl. Phys. Chem., 2014, vol. 458,part 2, pp. 153–157.

    Article  CAS  Google Scholar 

  8. Furman, A.A., Neorganicheskie khloridy (khimiya i tekhnologiya) [Inorganic Chlorides (Chemistry and Technology)], Moscow: Khimiya, 1980.

    Google Scholar 

  9. Ormont, B.F., Strutkury neorganicheskikh veshchestv (Structures of Inorganic Substances), Moscow: Tekhteorizdat, 1950.

    Google Scholar 

  10. Korshunov, B.G. and Stefanyuk, S.L., Vvedenie v khlornuyu metallurgiyu redkhikh elementov (Introduction to Chlorine Metallurgy of Rare Elements), Leningrad: Metallurgiya, 1970.

    Google Scholar 

  11. Cambaz, Z.G., Yushin, G.N., and Gogotsi, Y., J. Am. Ceram. Soc., 2006, vol. 89, no. 2, pp. 509–514.

    Article  CAS  Google Scholar 

  12. Almjasheva, O.V., Fedorov, B.A., Smirnov, A.V., and Gusarov, V.V., Nanosystems: Physics, Chemistry, Mathematics, 2010, vol. 1, no. 1, pp. 26–36.

    Google Scholar 

  13. Evans, R., Marconi, U.M.B., and Tarazona, P., J. Chem. Soc., Faraday Trans. II, 1986, vol. 82, pp. 1763–1787.

    Article  Google Scholar 

  14. Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption. Texture of Disperse and Porous Materials), Novosibirsk: Nauka, 1999.

    Google Scholar 

  15. Kravchik, A.E., Kukushkina, J.A., Sokolov, V.V., and Tereshchenko, G.F., Carbon, 2006, vol. 44, no. 15, pp. 3263–3268.

    Article  CAS  Google Scholar 

  16. Kravchik, A.E., Kukushkina, Yu.A., Sokolov, V.V., et al., Russ. J. Appl. Chem., 2008, vol. 81, no. 10, pp. 1733–1739.

    Article  CAS  Google Scholar 

  17. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, London: Academic, 1982, 2nd ed.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ioffe Physicotechnical Institute, Russian Academy of Sciences, ul. Politekhnicheskaya 26, St. Petersburg, 194021, Russia

    Yu. A. Kukushkina, V. V. Sokolov & M. V. Tomkovich

Authors
  1. Yu. A. Kukushkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Tomkovich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. V. Tomkovich.

Additional information

Original Russian Text © Yu.A. Kukushkina, V.V. Sokolov, M.V. Tomkovich, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1466–1473.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kukushkina, Y.A., Sokolov, V.V. & Tomkovich, M.V. Nanoporous carbon prepared by thermochemical treatment of carbide with chlorine. Russ J Appl Chem 87, 1517–1523 (2014). https://doi.org/10.1134/S107042721410019X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107042721410019X

Keywords

Search

Navigation