Skip to main content
SpringerLink
Log in

Catalytic coatings of new generation based on Mo2C and a microstructured reactor for steam conversion of carbon monoxide

  • Catalysis
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Cathodic processes occurring in the course of molybdenum hemicarbide synthesis on molybdenum supports (Mo2C/Mo) were studied by cyclic voltammetry. The coatings synthesized were tested as catalysts in steam conversion of carbon monoxide. The catalytic activity of the Mo2C/Mo system in this reaction is higher by 1–3 orders of magnitude than that of the commercial catalyst Cu/ZnO/Al2O3. A microstructured heat-exchanging reactor was designed and fabricated on the basis of the kinetic data obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Patt, J., Moon, D.-J., Phillips, C., and Thompson, L., Catal. Lett., 2000, vol. 65, no. 4, pp. 193–195.

    Article  CAS  Google Scholar 

  2. Moon, D.-J. and Ryu, J.W., Catal. Lett., 2004, vol. 92, nos. 1–2, pp. 17–24.

    Article  CAS  Google Scholar 

  3. Lee, J.S., Oyama, S.T., and Boudart, M., J. Catal., 1987, vol. 106, no. 1, pp. 125–133.

    Article  CAS  Google Scholar 

  4. LaMont, D.C., Gilligan, A.J., Darujati, A.R.S., et al., Appl. Catal. A, 2003, vol. 255, no. 2, pp. 239–253.

    Article  CAS  Google Scholar 

  5. Darujati, A.R.S., LaMont, D.C., and Thomson, W.J., Appl. Catal. A, 2003, vol. 253, no. 2, pp. 397–407.

    Article  CAS  Google Scholar 

  6. Zhu, Q., Zhang, B., Zhao, J., et al., J. Mol. Catal. A, 2004, vol. 213, no. 2, pp. 199–205.

    Article  CAS  Google Scholar 

  7. Graves, A.D. and Inman, D., Nature, 1965, vol. 208, no. 5009, pp. 481–486.

    Article  CAS  Google Scholar 

  8. Ivanovskii, L.E. and Nekrasov, V.N., Gazy i ionnye rasplavy (Gases and Ionic Melts), Moscow: Nauka, 1979.

    Google Scholar 

  9. Lovering, D.G., Molten Salts Technology, New York: Plenum, 1982.

    Book  Google Scholar 

  10. Fedorov, G.B. and Smirnov, E.A., Diffuziya v reaktornykh materialakh (Diffusion in Reactor Materials), Moscow: Atomizdat, 1978.

    Google Scholar 

  11. Kuznetsov, S.A., Dubrovskiy, A.R., Rebrov, E.V., et al., Z. Naturforsch. (a), 2007, vol. 62, nos. 10–11, pp. 647–654.

    CAS  Google Scholar 

  12. Rebrov, E.V., Kuznetsov, S.A., De Croon, M.H.J.M., et al., Catal. Today, 2007, vol. 125, nos. 1–2, pp. 86–96.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, Akademgorodok 26a, Apatity, Murmansk oblast, 184209, Russia

    A. R. Dubrovskii & S. A. Kuznetsov

  2. School of Chemistry and Chemical Engineering, Queen’s University of Belfast, Belfast, Northern Ireland, UK

    E. V. Rebrov

  3. Laboratory of Chemical Reactors, Eindhoven University of Technology, Eindhoven, Netherlands

    J. C. Schouten

Authors
  1. A. R. Dubrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Rebrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. C. Schouten
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. R. Dubrovskii.

Additional information

Original Russian Text © A.R. Dubrovskii, S.A. Kuznetsov, E.V. Rebrov, J.C. Schouten, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 612–618.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dubrovskii, A.R., Kuznetsov, S.A., Rebrov, E.V. et al. Catalytic coatings of new generation based on Mo2C and a microstructured reactor for steam conversion of carbon monoxide. Russ J Appl Chem 87, 601–607 (2014). https://doi.org/10.1134/S1070427214050115

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214050115

Keywords

Search

Navigation