Skip to main content
SpringerLink
Log in

Use of composites based on boron nitride in combined photocatalytic process for generation of hydrogen and degradation of soluble organic substances

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Possibility of using composites based on boron nitride in combined photocatalytic processes for degradation of soluble organic substances and generation of hydrogen was examined. The hydrogen evolution rate and output capacity of the composites under study in release of hydrogen from aqueous solutions of formic and oxalic acids and hydrazine under irradiation with visible and UV light were evaluated. It is shown that the highest efficiency of generation of molecular hydrogen is achieved in photodecomposition of hydrazine and oxalic acid with a composite whose phase composition includes iron and a set of semiconductor carbides (Fe3C, MgC2, Al4C3, SiC).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Patsoura, A., Kondarides, D., and Verykios, X., Catal. Today, 2007, vol. 124, no. 3, pp. 94–102.

    Article  CAS  Google Scholar 

  2. Liu, Y., Zhou, B., Bai, J., et al., Appl. Catal. B: Environ., 2009, vol. 89, nos. 1–2, pp. 142–148.

    CAS  Google Scholar 

  3. Teets, T.S. and Nocera, D.G., Chem. Commun., 2011, vol. 47, pp. 9268–9274.

    Article  CAS  Google Scholar 

  4. Kondarides, D.I., Patsoura, A., and Verykios, X.E., J. Adv. Oxid. Technol., 2010, no. 13, pp. 118–124.

    Google Scholar 

  5. Chiarello, G.L., Selli, E., and Forni, L., Appl. Catal. B: Environ., 2008, vol. 84, pp. 332–339.

    Article  CAS  Google Scholar 

  6. Daskalaki, V.M., Antoniadou, M., Li Puma, G., et al., Environ. Sci. Technol., 2010, no. 44, pp. 7200–7205.

    Google Scholar 

  7. Deng-Wei Jing, Wen-Dong Tang, Chan-Juan Xing, and Lie-Jin Guo, J. Fuel Chem. Technol., 2011, vol. 39, no. 2, pp. 135–139.

    Article  Google Scholar 

  8. Lee, G.-J., Manivel, A., Wu, J., et al., Ind. Eng. Chem. Res., 2013, vol. 52, no. 34, pp. 11904–11912.

    Article  CAS  Google Scholar 

  9. Hashimoto, A., Kawai, T., and Sakata, T., Nouveau J. de Chemie, 1984, vol. 8, no. 11, pp. 693–700.

    CAS  Google Scholar 

  10. Hasanov, N.H. and Mehrabova, M.A., Fizika, 2003, no. 3, pp. 12–13.

    Google Scholar 

  11. Karahan, S., Zahmakiran, M., and Ozkar, S., Dalton Trans., 2012, vol. 16, no. 41, pp. 4912.

    Article  Google Scholar 

  12. Junge, H., Boddien, A., Capitta, F., et al., Tetrahedron Lett., 2009, vol. 50, no. 14, pp. 1603–1606.

    Article  CAS  Google Scholar 

  13. Boddien, A., Loges, B., Gartner, F. et al., J. Am. Chem. Soc., 2010, vol. 132, no. 26, pp. 8924.

    Article  CAS  Google Scholar 

  14. Fellay, C., Dyson, P.J., and Laurenczy, G., Ang. Chem. Int Ed., 2008, vol. 47, no. 21, pp. 3966–3968.

    Article  CAS  Google Scholar 

  15. Skvortsova, L.N., Chukhlomina, L.N., Mokrousov, G.M., and Batalova, V.N., Russ. J. Appl. Chem., 2010, vol. 83, no. 9, pp. 1544–1547.

    Article  CAS  Google Scholar 

  16. Skvortsova, L.N., Chuklomina, L.N., Mokrousov, G.M., et al., Russ. J. Appl. Chem., 2012, vol. 85, no. 1, pp. 2021–2025.

    Article  Google Scholar 

  17. Skvortsova, L.N., Chuklomina, L.N., Mokrousov, G.M., and Krotov, A.E., Russ. J. Appl. Chem., 2013, vol. 86, no. 1, pp. 37–41.

    Article  CAS  Google Scholar 

  18. Junge, H., Boddien A., Capitta, F., et al., Tetrahedron Lett., 2009, vol. 50, no. 14, pp. 1603–1606.

    Article  CAS  Google Scholar 

  19. Fellay, C., Dyson, P.J., and Laurenczy, G.A., Ang. Chem. Int. Ed., 2008, vol. 47, no. 21, pp. 3966–3968.

    Article  CAS  Google Scholar 

  20. Loges, B., Boddien, A., Junge, H., and Beller, M., Ang. Chem. Int. Ed., 2008, vol. 47, no. 21, p. 3962.

    Article  Google Scholar 

  21. Hislop, K.A. and Bolton, J.R., Environ. Sci. Technol., 1999, no. 33, pp. 3119–3126.

    Google Scholar 

  22. Ghiselli, G., Jardim, W.F., Litter, M.I., and Mansilla, H.D., J. Rhotochem. Photobiol. A: Chem., 2004, vol. 167, pp. 59–67.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tomsk State University, pr. Lenina 36, Tomsk, 634050, Russia

    L. N. Skvortsova, V. N. Batalova & G. M. Mokrousov

  2. Department of Structural Macrokinetics, Tomsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademicheskii pr.10/4, Tomsk, 634021, Russia

    L. N. Chukhlomina

Authors
  1. L. N. Skvortsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Batalova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. N. Chukhlomina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. M. Mokrousov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. N. Skvortsova.

Additional information

Original Russian Text © L.N. Skvortsova, V.N. Batalova, L.N. Chukhlomina, G.M. Mokrousov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 569–575.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Skvortsova, L.N., Batalova, V.N., Chukhlomina, L.N. et al. Use of composites based on boron nitride in combined photocatalytic process for generation of hydrogen and degradation of soluble organic substances. Russ J Appl Chem 87, 561–566 (2014). https://doi.org/10.1134/S1070427214050048

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214050048

Keywords

Search

Navigation