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Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The kinetics of radiation-initiated telomerization of tetrafluoroethylene in a 1,2-dibromotetrafluoroethane solution at a constant concentration (pressure) of the monomer in the reactor was studied. The properties, molecular structure, and morphology of the telomers were studied by IR spectroscopy, scanning electron microscopy, and elemental and thermal gravimetric analyses. The synthesized telomers show promise for the development of fluoropolymeric nanocomposites and protective hydrophobic and antifriction coatings.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, ul. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    G. A. Kichigina, A. I. Bol’shakov, P. P. Kushch & D. P. Kiryukhin

Authors
  1. G. A. Kichigina
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  2. A. I. Bol’shakov
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  3. P. P. Kushch
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  4. D. P. Kiryukhin
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Corresponding author

Correspondence to G. A. Kichigina.

Additional information

Original Russian Text © G.A. Kichigina, A.I. Bol’shakov, P.P. Kushch, D.P. Kiryukhin, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 4, pp. 528–535.

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Kichigina, G.A., Bol’shakov, A.I., Kushch, P.P. et al. Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor. Russ J Appl Chem 87, 518–524 (2014). https://doi.org/10.1134/S10704272140400211

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  • DOI: https://doi.org/10.1134/S10704272140400211

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