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Electrodialytic separation of cobalt(II) and nickel(II) using liquid membranes based on tri-n-octylamine and trialkylbenzylammonium chloride

  • Applied Electrochemistry and Corrosion Protection of Metals
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Abstract

Electrodialytic separation of Co(II) and Ni(II) in the course of their transfer from 3–4 M HCl solutions into dilute solutions of various acids using liquid membranes that contain anion-exchange carriers was studied. The influence exerted on the metal transport rate and separation efficiency by the compositions of the feed and receiving aqueous solutions and of liquid membranes and by the electrodialysis current density was examined. Under optimal conditions, in metal recovery from a solution containing an equimolar mixture of 0.01 M CoCl2 and NiCl2, the separation factor βCo/Ni is 147; when nickel in the feed solution is in excess, it reaches 330, and when cobalt(II) is in excess, it exceeds 400.

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References

  1. Perel’man, F.M. and Zvorykin, A.Ya., Kobal’t i nikel’ (Cobalt and Nickel), Moscow: Nauka, 1975.

    Google Scholar 

  2. Shchukarev, S.A., Andreev, S.N., and Burkov, K.A., Dokl. Akad. Nauk SSSR, 1962, vol. 44, no. 2, p. 371.

    Google Scholar 

  3. Shmidt, V.S., Ekstraktsiya aminami (Extraction with Amines), Moscow: Atomizdat, 1980.

    Google Scholar 

  4. Suruku, A., Eyupoglu, V., and Tutkun, O., J. Ind. Eng. Chem., 2012, vol. 18, no. 2, p. 629.

    Article  Google Scholar 

  5. Suruku, A., Eyupoglu, V., and Tutkun, O., Desalination, 2010, vol. 250, no. 3, p. 1155.

    Article  Google Scholar 

  6. Kumbasar, R.A., J. Ind. Eng. Chem., 2010, vol. 16, no. 3, p. 448.

    Article  CAS  Google Scholar 

  7. Fang, J., Li, M., and Xu, Z., Sep. Sci. Technol., 2003, vol. 38, no. 14, p. 3553.

    Article  CAS  Google Scholar 

  8. Kumbasar, R.A. and Tutkun, O., Desalination, 2008, vol. 224, nos. 1–3, p. 201.

    Article  CAS  Google Scholar 

  9. Kumbasar, R.A., J. Membr. Sci., 2009, vol. 333, nos. 1–2, p. 118.

    Article  CAS  Google Scholar 

  10. Pospieh, B. and Walkowiak, W., Sep. Purif. Technol., 2007, vol. 57, no. 3, p. 461.

    Article  Google Scholar 

  11. Purin, B.A., Proc. Int. Solvent Extraction Symp., Moscow, 1998, p. 234.

    Google Scholar 

  12. Sadyrbaeva, T.Zh. and Purin, B.A., Latv. KĪm. Ž., 1993, no. 3, p. 301.

    Google Scholar 

  13. Sadyrbaeva, T.Zh., Zh. Prikl. Khim., 2003, vol. 76, no. 1, p. 78.

    Google Scholar 

  14. Sadyrbaeva, T.Zh., Sci. J. Riga Tech. Univ., Mater. Sci. Appl. Chem., 2007, vol. 15, p. 1262.

    Google Scholar 

  15. Marczenko, Z., Kolorymetryczne oznaczanie pierwiastkow, Warsaw: Naukowa-Techniczne, 1968.

    Google Scholar 

  16. Golubev, V.N. and Purin, B.A., Dokl. Akad. Nauk SSSR, 1977, vol. 232, no. 6, p. 1340.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Riga Technical University, Salaspils, Latvia

    T. Zh. Sadyrbaeva

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  1. T. Zh. Sadyrbaeva
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Correspondence to T. Zh. Sadyrbaeva.

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Original Russian Text © T.Zh. Sadyrbaeva, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 2, pp. 202–208.

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Sadyrbaeva, T.Z. Electrodialytic separation of cobalt(II) and nickel(II) using liquid membranes based on tri-n-octylamine and trialkylbenzylammonium chloride. Russ J Appl Chem 86, 186–191 (2013). https://doi.org/10.1134/S1070427213020109

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  • DOI: https://doi.org/10.1134/S1070427213020109

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