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Homogeneous oxidation of hydrogen selenide with ozone in an argon-oxygen medium

  • Physicochemical Studies of Systems and Processes
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Abstract

Homogeneous oxidation of hydrogen selenide with ozone present in deficiency was studied. One of the reaction products is elemental selenium Se8, which can be formed by multistep radical-chain polycondensation of hydrogen selenide. One mole of ozone is consumed per mole of hydrogen selenide. The observed rate constant of the reaction of hydrogen selenide with ozone at 20 ± 1°C is no less than (1.9 ± 0.2) × 105 l mol−1 s−1.

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Authors and Affiliations

  1. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, Nizhni Novgorod, Russia

    A. V. Belyaev, A. Yu. Sozin, Yu. A. Aleksandrov & M. F. Churbanov

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  1. A. V. Belyaev
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  2. A. Yu. Sozin
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  3. Yu. A. Aleksandrov
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  4. M. F. Churbanov
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Correspondence to A. V. Belyaev.

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Original Russian Text © A.V. Belyaev, A.Yu. Sozin, Yu.A. Aleksandrov, M.F. Churbanov, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 2034–2037.

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Belyaev, A.V., Sozin, A.Y., Aleksandrov, Y.A. et al. Homogeneous oxidation of hydrogen selenide with ozone in an argon-oxygen medium. Russ J Appl Chem 85, 1919–1922 (2012). https://doi.org/10.1134/S107042721212021X

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  • DOI: https://doi.org/10.1134/S107042721212021X

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