Abstract
The possibility of surface modification of polyethylene terephthalate granulate by fluorinated prepolymers which contain urethane groups was examined. A depth of a modified surface layer (12–18 μm) was found. The modified system reduces a crystallinity of a polymer and varies thermal transitions, which characterize a mobility of structural units of a macromolecular chain. An increase in hydrolytic and thermal-oxidative stability of the modified polyethylene terephthalate was demonstrated.
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References
Brooks, D. and Giles, G., PET Packaging Technology, Blackwell, 2002.
Petukhov, B.V., Poliefirnye volokna (Polyester Fibers), Moscow: Khimiya, 1976.
Mikitaev A.K., Doroshenko Yu.E., Aid Alaa Ibrakhim Akhmad, et al., Khim. Promst’ Segodnya, 2006, no. 12, pp. 36–45.
Kudashev, S.V., Cand. Sci. (Chem.) Dissertation, Volgograd, 2011.
Ponomarenko, V.A., Krukovskii, S.P., and Alybina, A.Yu., Ftorsoderzhashchie geterotsepnye polimery (Fluorine-containing Heterochain Polymers), Moscow: Nauka, 1973.
Rakhimova, N.A. and Kudashev, S.V., Izv. VolgGTU, no. 8, Volgograd. Tekhn. Univ., 2011, pp. 133–140.
Kudashev, S.V. and Rakhimova, N.A., Abstracts of Papers, Tret’ya vseros. shkola-seminar studentov, aspirantov i molodykh uchenykh po napravleniyu “Nanoinzheneriya” (3rd All-Rusian Workshop-School of Students, Graduate Students, and Young Scientists on “Nanoengineering”), Moscow, 2010, pp. 66–70.
Bershtein, V.A. and Egorov, V.M., Differentsial’naya skaniruyushchaya kalorimetriya v fizikokhimii polimerov (Differential Scanning Calorimetry in the Physical Chemistry of Polymers), Leningrad: Khimiya, 1990.
Entelis, S.G. and Nesterov, O.V., Usp. Khim., 1966, vol. 35, no. 12, pp. 2178–2203.
Pretsch, E., Buhlmann, P., and Affolter, C., Structure Determination of Organic Compounds, Springer-Verlag, 2000.
Kuptsov, A.Kh. and Zhizhin, G.N., Fur’e-spektry kombinatsionnogo rasseyaniya i infrakrasnogo pogloshcheniya polimerov (Fourier Spectra of the Raman and Infrared Absorption of Polymers), Moscow: Fizmatlit, 2001.
Tiger, R.P., Sarynina, L.I., and Entelis, S.G., Usp. Khim., 1972, vol. 41, no. 9, pp. 1672–1695.
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Original Russian Text © S.V. Kudashev, U.R. Urmantsev, G.V. Selezneva, N.A. Rakhimova, V.F. Zheltobryukhov, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 11, pp. 1860–1866.
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Kudashev, S.V., Urmantsev, U.R., Selezneva, G.V. et al. Surface modification of granules of polyethylene terephthalate by fluorine-containing urethanes. Russ J Appl Chem 85, 1764–1770 (2012). https://doi.org/10.1134/S1070427212100225
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DOI: https://doi.org/10.1134/S1070427212100225