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Synthesis and thermolysis of substitutional solid solutions (Cu1−y M y )2(OH)PO4·xH2O (x = 0.1−0.2; M = Zn, Co, Ni)

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Substitutional solid solutions (Cu1−y Zn y )2(OH)PO4·xH2O (0 ≤ y ⩽ 0.26, x = 0.1−0.2), (Cu1−y Co y )2(OH)PO4·xH2O (0 ≤ y ≤ 0.10, x = 0.1−0.2), and (Cu1−y Ni y )2(OH)PO4·xH2O (0 ≤ y ≤ 0.08, x = 0.1−0.2) were synthesized. The unit cell parameters of the resulting phosphates were determined, and their IR absorption spectra were measured. The reactants were H3PO4 and mixtures of hydrous carbonates of the appropriate metals. Thermolysis of the solid solutions was examined with (Cu1−y Co y )2(OH)PO4·xH2O (0 ≤ y ≤ 0.10, x = 0.1−0.2) as an example.

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Authors and Affiliations

  1. Shevchenko Kiev National University, Kiev, Ukraine

    V. N. Viter

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  1. V. N. Viter
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Original Russian Text © V.N. Viter, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 12, pp. 1952–1956.

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Viter, V.N. Synthesis and thermolysis of substitutional solid solutions (Cu1−y M y )2(OH)PO4·xH2O (x = 0.1−0.2; M = Zn, Co, Ni). Russ J Appl Chem 82, 2093–2097 (2009). https://doi.org/10.1134/S1070427209120039

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  • DOI: https://doi.org/10.1134/S1070427209120039

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