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Zur Kenntnis der Kupferphosphate

Preparation and identification of copper(II)-phosphates

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Among the sparingly soluble copper(II)-phophates the existence of CuHPO4·H2O and of Cu4H(PO4)3·3 H2O was verified by X-ray powder-diagrams, other statements on preparations and X-ray diagrams were corrected. Cu3(PO4)2·3 H2O apparently does not exist. Structural analogies of Cu4H(PO4)3·3 H2O and CaHPO4·2 H2O may offer an explanation for the restraint hydrolysis of the calcium salt in presence of low copper concentrations. Pseudomalachite was synthesised hydrothermally.

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Universität Innsbruck, Innrain 52 a, A-6020, Innsbruck, Österreich

    Erich Hayek, Peter Reinthaler & Joachim Adamietz

Authors
  1. Erich Hayek
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  2. Peter Reinthaler
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  3. Joachim Adamietz
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Hayek, E., Reinthaler, P. & Adamietz, J. Zur Kenntnis der Kupferphosphate. Monatshefte für Chemie 107, 557–563 (1976). https://doi.org/10.1007/BF00906886

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  • DOI: https://doi.org/10.1007/BF00906886

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