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Effect of the nature of anions of aluminum salts used to synthesize a precursor of the Al2O3-ZrO2 ceramics on the stabilization of the tetragonal modification of zirconium dioxide

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Samples of a precursor for an aluminum oxide ceramics reinforced with zirconium oxide were synthesized by hydrolysis of various aluminum salts in the presence of a ZrO2 sol under conditions of urea decomposition at 90°C and pH < 4 maintained, with hydrolysis products deposited onto the surface of ZrO2 sol particles. It was found that the nature of a salt anion affects the interaction of hydrolysis products of the aluminum cation with the surface of ZrO2 sol particles. The structure of products formed in thermal treatment of samples of a precursor for Al2O3-ZrO2 (T = 1250°C) was characterized by X-ray phase analysis and scanning electron microscopy. The phase transition temperatures of the oxides Al2O3 and ZrO2 contained in the precursor were estimated using the results of thermal analysis of the samples in the temperature range 20–1300°C.

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References

  1. Podzorova, L.I., Il’icheva, A.A., and Pen’kova, O.I., Ogneupory Tekhn. Keram., 2005, no. 11, pp. 2–5.

  2. Shevchenko, A.V., Ruban, A.K., and Dudnik, E.V., Ogneupory Tekhn. Keram., 2000, no. 9, pp. 2–8.

  3. Podzorova, L.I., Il’icheva, A.A., Mikhailina, N.A., et al., Neorg. Mater., 2002, vol. 38, no. 12, pp. 1455–1461.

    Article  Google Scholar 

  4. Andrievskii, R.A., Ross. Khim. Zh., 2002, vol. 46, no. 5, pp. 50–56.

    CAS  Google Scholar 

  5. Zharnyl’skaya, A.L., Vol’khin, V.V., Shcherban’, M.G., and Reuther, H., Zh. Prikl. Khim., 2008, no. 7, pp. 1069–1074.

  6. Tret’yakov, Yu.D., Usp. Khim., 2004, vol. 73, no. 9, pp. 899–916.

    Google Scholar 

  7. Bi, S., Wang, C., Cao, Q., et al., Coord. Chem. Rev., 2004, vol. 248, pp. 441–455.

    Article  CAS  Google Scholar 

  8. Messing, G.L. and Kumagai, M., J. Am. Ceram. Soc., 1989, vol. 72, no. 1, pp. 40–44.

    Article  CAS  Google Scholar 

  9. Srdic, V.V. and Radonjic, L., J. Am. Ceram. Soc., 1997, vol. 80, no. 8, pp. 2056–2060.

    Article  CAS  Google Scholar 

  10. Garvie, R.S. and Nicholson, P.S., J. Am. Ceram. Soc., 1972, vol. 55, no. 6, pp. 303–305.

    Article  CAS  Google Scholar 

  11. Mitra, N., Vijayan, K., Pramila Bai, B.N., et al., J. Am. Ceram. Soc., 1993, vol. 76, no. 2, pp. 533–535.

    Article  CAS  Google Scholar 

  12. Rentgenografiya: Spetspraktikum (X-ray Diffraction Analysis: Special Practical Course), Katsnel’son, A.A., Ed., Moscow: Mosk. Gos. Univ., 1986.

    Google Scholar 

  13. Feng, C., Wei, Q., Wang, S., et al., Colloids Surfaces A: Physicochem. Eng. Aspects, 2007, vol. 303, pp. 241–248.

    Article  CAS  Google Scholar 

  14. Stumm, W. and Morgan, J.J., Aquatic Chemistry, New York: J. Wiley & Sons, Inc., 1996.

    Google Scholar 

  15. Ochs, M., Cosovic, B., and Stumm, W., Geochim. Cosmochim. Acta, 1994, vol.58, no. 2, pp. 639–650.

    Article  CAS  Google Scholar 

  16. Summ, B.D. and Ivanova, N.I., Usp. Khim., 2000, vol. 69, no. 11, pp. 995–1008.

    Google Scholar 

  17. Nazarov, V.V., Yuan’ Dou Shen, and Frolov, Yu.G., Kolloid. Zh., 1992, vol. 54, no. 3, pp.119–122.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Perm State Technical University, Perm, Russia

    A. L. Zharnyl’skaya & V. V. Vol’khin

  2. Forschungszentrum Dresden-Rossendorf, Dresden, Germany

    H. Reuther

Authors
  1. A. L. Zharnyl’skaya
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  2. V. V. Vol’khin
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  3. H. Reuther
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Additional information

Original Russian Text © A.L. Zharnyl’skaya, V.V. Vol’khin, H. Reuther, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 8, pp. 1268–1272.

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Zharnyl’skaya, A.L., Vol’khin, V.V. & Reuther, H. Effect of the nature of anions of aluminum salts used to synthesize a precursor of the Al2O3-ZrO2 ceramics on the stabilization of the tetragonal modification of zirconium dioxide. Russ J Appl Chem 82, 1364–1369 (2009). https://doi.org/10.1134/S1070427209080084

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  • DOI: https://doi.org/10.1134/S1070427209080084

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