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Phase Transformations of Zirconium Dioxide and Crystal Growth During Heat Treatment of the ZrO2(CeO2,Y2O3)–La0.85Y0.15Al11O18–Al2O3 System

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Abstract

A compound material with a matrix based on zirconium dioxide stabilized with cerium and yttrium oxides, filled with layered particles of lanthanum hexaaluminate and reinforced with aluminum oxide nanofibers, was obtained. The values of the activation energy for the formation of ZrO2 polymorphic modifications, the size of the crystallites of the compound material matrix were determined; the phase formation and the crystallinity degree of the phases formed in the ZrO2(CeO2,Y2O3)–La0.85Y0.15Al11O18–Al2O3 system were studied in relation to the joint introduction of stabilizing additives and Al2O3 nanofibers.

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ACKNOWLEDGMENTS

The authors express their gratitude to E.M. Tropnikov (Institute of Geology of the Federal Research Center of the Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences) and A.A. Utkin (Pitirim Sorokin Syktyvkar State University) for taking electron micrographs of surfaces of samples on a scanning electron microscope and for their X-ray spectral analysis.

Funding

The work was financially supported within the framework of the scientific project of the Scientific and Educational Center (no. 122040100040-0) and research work (topic no. 1021051101544-1-1.4.3) using the equipment of the Center for Collective Use “Chemistry” of the Institute of Chemistry of the Komi Federal Research Center of the Scientific Center of the Ural Branch of the Russian Academy of Sciences.

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  1. Institute of Chemistry of the Federal Research Center of the Komi Research Center of the Ural Branch of the Russian Academy of Sciences, 167982, Syktyvkar, Russia

    A. Yu. Bugaeva, L. Yu. Nazarova, V. A. Belyi & Yu. I. Ryabkov

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  1. A. Yu. Bugaeva
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  2. L. Yu. Nazarova
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  3. V. A. Belyi
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Correspondence to A. Yu. Bugaeva.

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Bugaeva, A.Y., Nazarova, L.Y., Belyi, V.A. et al. Phase Transformations of Zirconium Dioxide and Crystal Growth During Heat Treatment of the ZrO2(CeO2,Y2O3)–La0.85Y0.15Al11O18–Al2O3 System. Russ J Gen Chem 92, 1488–1497 (2022). https://doi.org/10.1134/S1070363222080175

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