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Synthesis and study of solid solutions between cobalt and nickel phosphates with varied degree of anion protonation

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Continuous substitutional solid solutions between cobalt and nickel phosphates with varied degree of anion protonation were obtained: Co1−x Ni x HPO4·1.5H2O and (Co1−x Ni x )3(PO4)2·8H2O, where 0 ≤ x ≤ 1.00. The thermolysis of the solid solutions was studied by the example of Co1−x Ni x HPO4·1.5H2O. The phases synthesized were compared with the previously described continuous solid solution Co1−x Ni x (H2PO4)2·2H2O.

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References

  1. Gao, D. and Gao, Q., Microp. Mesop. Mater., 2005, vol. 85, no. 3, p. 365.

    Article  CAS  Google Scholar 

  2. Ghorai, T.K., Dhak, D., Azizan, A., and Pramanik, P., Mater. Sci. Eng., Ser. B, 2005, vol. 121, no. 3, p. 216.

    Article  Google Scholar 

  3. Legrouri, A., Lenzi, J., and Lenzi, M., Mater. Chem. Phys., 1994, vol. 38, no. 1, p. 94.

    Article  CAS  Google Scholar 

  4. Legrouri, A., Lenzi, J., and Lenzi, M., React. Kinet. Catal. Lett., 1992, vol. 48, no. 2, p. 349.

    Article  CAS  Google Scholar 

  5. Aaddane, A., Kacimi, M., and Ziyad, M., Catal. Lett., 2001, vol. 73, no. 1, p. 47.

    Article  CAS  Google Scholar 

  6. Abu, I.I. and Smith, K.J., Appl. Catal. A: General, 2007, vol. 328, no. 1, p. 58.

    Article  CAS  Google Scholar 

  7. Song, L., Li, W., Wang, G., et al., Catal. Today, 2007, vol. 125, nos. 3–4, p. 137.

    Article  CAS  Google Scholar 

  8. Nagai, M., Fukiage, T., and Kurata, Sh., Catal. Today, 2005, vol. 106, nos. 1–4, p. 201.

    Article  CAS  Google Scholar 

  9. Sun, F., Wu, W., Wu, Z., et al., J. Catal., 2004, vol. 228, no. 2, p. 298.

    Article  CAS  Google Scholar 

  10. Korsunskii, L.F., Kalinskaya, T.V., and Stepin, S.N., Neorganicheskie pigmenty (Inorganic Pigments), St. Petersburg: Khimiya, 1992.

    Google Scholar 

  11. JCPDS, Int. Center for Diffraction Data, nos. 39–698, 39–705, 39–706, 33–432, 33–951.

  12. Viter, V.N. and Nagornyi, P.G., Zh. Neorg. Khim., 2007, vol. 52, no. 1, p. 19.

    CAS  Google Scholar 

  13. Konstant, Z.A. and Dindune, A.P., Fosfaty dvukhvalentnykh metallov (Phosphates of Bivalent Metals), Riga: Zinatne, 1987.

    Google Scholar 

  14. Pyatnitskii, I.V., Analiticheskaya khimiya kobal’ta (Analytical Chemistry of Cobalt), Moscow: Nauka, 1965.

    Google Scholar 

  15. Zhivopistsev, V.P. and Selezneva, E.A., Analiticheskaya khimiya tsinka (Analytical Chemistry of Zinc), Moscow: Nauka, 1975.

    Google Scholar 

  16. Qualitative Inorganic Analysis, Charlot, G., Ed., Thomas Press, 2007.

  17. GOST (State Standard) 20851-75: Mineral Fertilizers: Methods for Analysis, Moscow: Izd. Standartov, 1986.

    Google Scholar 

  18. Pechkovskii, V.V., Mel’nikova, R.Ya., Dzyuba, E.D., et al., Atlas infrakrasnykh spektrov fosfatov: Ortofosfaty (Atlas of IR Spectra of Phosphates), Moscow: Nauka, 1981.

    Google Scholar 

  19. The Microscopical Characters of Artificial Inorganic Solid Substances: Optical Properties of Artificial Minerals, Winchell, A.N., and Winchell, H., Eds., Academic Press, 1964.

  20. Nord, A.G., Acta Chem. Scand., 1982, vol. A36, no. 2, p. 95.

    Article  CAS  Google Scholar 

  21. Nord, A.G., Mater. Res. Bull., 1981, vol. 16, p. 1121.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Shevchenko National University, Kiev, Ukraine

    V. N. Viter & P. G. Nagornyi

Authors
  1. V. N. Viter
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  2. P. G. Nagornyi
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Original Russian Text © V.N. Viter, P.G. Nagornyi, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 6, pp. 881–885.

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Viter, V.N., Nagornyi, P.G. Synthesis and study of solid solutions between cobalt and nickel phosphates with varied degree of anion protonation. Russ J Appl Chem 82, 935–939 (2009). https://doi.org/10.1134/S1070427209060019

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  • DOI: https://doi.org/10.1134/S1070427209060019

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