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Irreversible solid-state metal ion exchange in cobalt(II) metal–organic nanocapsules synthesized by green mechanochemical process

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Abstract

Abstract

Irreversible solid-state conversion of Co(II) metal–organic nanocapsule [Co2(bda)2(bpy)2] (1), [bda2− = 2,2′-biphenyl dicarboxylate and bpy = 2,2′-bipyridine], prepared by mechanochemical procedure with empty pore and lozenge-shaped microcube morphology similar to [Cu2(bda)2(bpy)2]∙4H2O (2) analogue with agglomerated nanostructure morphology was studied. The structure of 1 is exactly the same as 2 and the metal ion has distorted octahedral coordination in both of them. In addition to the same structures of 1 and 2, the similar crystal data of them also approved that this reaction can occur in solid state by cation exchange process. Solid-state cation exchange processes of these metal–organic nanocapsules were studied by IR spectroscopy, X-ray powder diffraction (XRD) and scanning electron microscopy (SEM).

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Acknowledgements

The authors would like to acknowledge the financial support of University of Tehran for this research under Grant Number 01/1/389845.

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Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Elham Mirzadeh & Kamran Akhbari

  2. Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand

    Anukorn Phuruangrat

Authors
  1. Elham Mirzadeh
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  2. Kamran Akhbari
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  3. Anukorn Phuruangrat
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Correspondence to Kamran Akhbari.

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Mirzadeh, E., Akhbari, K. & Phuruangrat, A. Irreversible solid-state metal ion exchange in cobalt(II) metal–organic nanocapsules synthesized by green mechanochemical process. J IRAN CHEM SOC 16, 707–714 (2019). https://doi.org/10.1007/s13738-018-1544-3

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  • DOI: https://doi.org/10.1007/s13738-018-1544-3

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