Abstract
Electrochemical method for arsenic determination at concentrations characteristic of inversion voltammetry was suggested. The method does not require calibration of the measuring instrument against standard solutions or application of the standard-additive technique. The method of no-reference inversion-volammetric determination is based on calculating the arsenic concentration in solution with the use of the preliminarily determined coulometric constant of an electrochemical cell.
Similar content being viewed by others
References
Vrednye khimicheskie veshchestva: Neorganicheskie soedineniya V–VIII grupp (Noxious Chemical Substances: Group V–VIII Inorganic Compounds), Leningrad: Khimiya, 1989.
He, Y., Zheng, Y., Ramnaraine, M., and Locke, D.C., Analyt. Chim. Acta, 2004, vol. 511, pp. 55–61.
Gong, Z., Lu, X., Ma, M., Watt, C., and Le, C., Talanta, 2002, vol. 58, pp. 77–96.
Richardson, S., Analyt. Chem., 2001, vol. 73, pp. 2719–2734.
Melamed, D., Analyt. Chim. Acta, 2005, vol. 532, pp. 1–13.
Hung, D., Nekrassova, O., and Compton, R., Talanta, 2004, vol. 64, pp. 269–277.
Sun, Y.-C., Mierzwa, J., and Yang, M.-H., Talanta, 1997, vol. 44, pp. 1379–1387.
US Patent 5891322.
Sokolkov, S.V. and Zagorodnyuk, P.N., Zh. Ross. Khim., O-va im. D.I. Mendeleeva, 2001, vol. 45, pp. 78–82.
Jurica, L., Manova, A., and Beinrohr, E., Polish J. Environ. Studies, 2004, vol. 13, pp. 533–536.
Sheremet, A., Averyaskina, E., Chekmeneva, E., and Ermakov, S., Electroanalysis, 2007, vol. 19, pp. 2163–2165.
Ermakov, S.S., Sheremet, A.A., and Moskvin, L.N., Zh. Prikl. Khim., 2008, vol. 81, no. 3, pp. 434–436.
Ermakov, S.S, Tsapko, Y.V., and Chezhina, N.M., Abstracts of Papers, 12th Int. Conf. on Electroanalysis, Prague, June 16–19, 2008, p. 85.
RF Patent 2199734.
Ermakov, S.S., Chekmeneva, E.N., and Moskvin, L.N., Zh. Anal. Khim., 2007, vol. 62, pp. 89–94.
Zaichko, A.V., Ivanova, E.E., and Noskova, G.N., Zavod. Lab., 2005, vol. 71, pp. 19–23.
Zakharova, E.A., Deryabina, V.I., and Slepchenko, G.B., Zh. Anal. Khim., 2005, vol. 60, pp. 571–575.
Author information
Authors and Affiliations
Additional information
Original Russian Text © Yu.V. Tsapko, I.I. Tumkin, S.S. Ermakov, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 2, pp. 268–272.
Rights and permissions
About this article
Cite this article
Tsapko, Y.V., Tumkin, I.I. & Ermakov, S.S. Determination of arsenic in aqueous solutions by no-reference inversion voltammetry. Russ J Appl Chem 82, 262–266 (2009). https://doi.org/10.1134/S1070427209020189
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427209020189