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N-hydroxyphthalimide-initiated radical polymerization of vinyl monomers

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

The initiating ability of N-hydroxyphthalimide in polymerization of methyl methacrylate and acrylonitrile was examined. For the polymerization of methyl methacrylate, the initial polymerization rates and activation energies were determined, and the dependences of the polymerization rates on the initiator and monomer concentrations were evaluated. An initiation mechanism was suggested.

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Authors and Affiliations

  1. Litvinenko Institute of Physicoorganic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine

    I. A. Opeida, M. A. Kompanets, O. V. Kushch & A. G. Matvienko

Authors
  1. I. A. Opeida
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  2. M. A. Kompanets
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  3. O. V. Kushch
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  4. A. G. Matvienko
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Additional information

Original Russian Text © I.A. Opeida, M.A. Kompanets, O.V. Kushch, A.G. Matvienko, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 10, pp. 1688–1691.

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Opeida, I.A., Kompanets, M.A., Kushch, O.V. et al. N-hydroxyphthalimide-initiated radical polymerization of vinyl monomers. Russ J Appl Chem 80, 1717–1720 (2007). https://doi.org/10.1134/S1070427207100230

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  • DOI: https://doi.org/10.1134/S1070427207100230

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