Abstract
The mechanism of processes occurring when a low-molecular-weight compound interacts with a block copolymer is considered. The anomalous results obtained with the butadiene-styrene stationary phase are accounted for. The effect of modifying additives on the sorption properties of the polymer is examined.
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Kalinin, A.V. and Voznyakovskii, A.P., Zh. Prikl. Khim., 2006, vol. 79, no. 11, pp. 2022–2030.
Noshay, A. and McGrath, J.E., Block Copolymers, Overview and Critical Survey, New York: Academic, 1977.
Grigoryan, G.V., Polyester-Polysiloxane Block Co-Polymers, Cand. Sci. Dissertation, Leningrad, 1982.
Nesterov, A.E., Obrashchennaya gazovaya khromatografiya polimerov (Reverse Gas Chromatography of Polymers), Kiev: Naukova Dumka, 1988.
Voznyakovskii, A.P., Genkin, A.N., and Petrova, N.A., Abstracts of Papers, Sed’maya Vsesoyuznaya konferentsiya “Khimiya i primenenie kremniiorganicheskikh soedinenii” (Seventh All-Union Conf. “Chemistry and Applications of Organosilicon Compounds”), Tbilisi, November 20–23, 1990, vol. 2, p. 52.
Vakula, V.L. and Pritykin, L.M., Fizicheskaya khimiya adgezii polimerov (Physical Chemistry of Polymer Adhesion), Moscow: Khimiya, 1984.
Tager, A.A., Fizikokhimiya polimerov (Physical Chemistry of Polymers), Moscow: Khimiya, 1978.
Entsiklopediya polimerov (Polymer Encyclopedia), Kargin, V.A., Ed., Moscow: Sov. Entsiklopediya, 1972, vol. 1.
Kato, K., Polym. Eng. Sci., 1967, vol. 7, no. 1, p. 38.
Livingstone, S.E., The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum, Oxford: Pergamon, 1973.
Voznyakovskii, A.P., Genkin, A.N., Plyushch, A.V., and Petrova, N.A., Vysokomol. Soedin., 1986, vol. 28, no. 12, pp. 2621–2623.
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Original Russian Text © A.V. Kalinin, A.P. Voznyakovskii, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 9, pp. 1537–1542.
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Kalinin, A.V., Voznyakovskii, A.P. Application of reverse gas chromatography to studying the microheterogeneous structure of block copolymers. Russ J Appl Chem 80, 1570–1574 (2007). https://doi.org/10.1134/S1070427207090248
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DOI: https://doi.org/10.1134/S1070427207090248