Abstract
An integrated technology for manufacture of fullerenes was developed. It includes the following stages: synthesis of a fullerene black, extraction of a mixture of fullerenes from the black, preliminary separation of the mixture into concentrates enriched in C60 and C70 fullerenes, and production of C60 and C70 fullerenes of purity exceeding 99.5 and 98.0 wt %, respectively, from the concentrates.
Similar content being viewed by others
References
Howard, J.B., McKinnon, J.T., Johnson, M.E., et al., J. Phys. Chem., 1992, vol. 96, no. 16, pp. 6657–6662.
Taylor, R., Langley, G.J., Kroto, H.W., and Walton, D.R.M., Nature, 1993, vol. 366, no. 6457, pp. 728–731.
Fields, C.L., Pitts, J.R., Hale, M.J., et al., J. Phys. Chem., 1993, vol. 97, pp. 8701–8702.
Laska, L., Czech. J. Phys., 1993, vol. 43, no. 2, pp. 193–195.
Bubnov, V.P., Krainskii, I.S., Laukhina, E.E., and Yagubskii, E.B., Izv. Ross. Akad. Nauk., Ser. Khim., 1994, no. 5, pp. 805–809.
RF Patent 2 086 503.
RF Patent 2 139 241.
RF Patent 2 146 647.
RF Patent 2 234 457.
RF Certificate for Useful Model no. 25 317.
Parker, D.H., Wurz, P., Chatterjee, K., et al., J. Am. Chem. Soc., 1991, vol. 113, pp. 7499–7503.
RF Patent 2 107 536.
Sedov, V.P. and Shilin, V.A., Extraction of Fullerenes with a Solvent from Electric-Arc Carbon Black on a Pilot Installation, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2001, no. 2424.
Laukhina, E.E. and Bubnov, V.P., Izv. Ross. Akad. Nauk, Ser. Khim., 1995, no. 5, pp. 1223–1225.
Belousov, V.P., Belousova, I.M., Budtov, V.P., et al., Opt. Zh., 1997, vol. 64, no. 12, pp. 3–37.
Afanas’ev, D.V., Blinov, I.O., Bogdanov, A.A., et al., Zh. Tekh. Fiz., 1994, vol. 64, no. 10, pp. 76–90.
Afanas’ev, D.V., Bogdanov, A.A., Dyuzhev, G.A., and Kruglikov, A.A., Zh. Tekh. Fiz., 1997, vol. 67, no. 2, pp. 125–128.
Sedov, V.P. and Shilin, V.A., Experience in Manufacture of a Fullerene-Containing Carbon Black, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2001, no. 2433.
Krestinin, A.V. and Moravskii, A.P., Khim. Fiz., 1999, vol. 18, no. 3, pp. 58–66.
Bezmel’nitsyn, V.N., Eletskii, A.V., and Okun’, M.V., Usp. Fiz. Nauk, 1998, vol. 168, no. 11, pp. 1195–1220.
Eletskii, A.V., Teplofiz. Vys. Temp., 1996, vol. 34, no. 2, pp. 308–323.
RF Patent 2 124 473.
Moskalev, P.N., Sedov, V.P., and Grushko, Yu.S., Experience in Sublimation Recovery of Fullerenes from a Fullerene-Containing Carbon Black, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2001, no. 2423.
Zhou, X., Lin, J., Jin, Z., et al., Fullerene Sci. Technol., 1997, vol. 5, no. 1, pp. 285–290.
Beck, M.T. and Mandi, G., Fullerene Sci. Technol., 1997, vol. 5, no. 2, pp. 291–310.
Doome, R.J., Fonseca, A., Richter, H., et al., J. Phys. Chem. Solids, 1997, vol. 58, no. 11, pp. 1839–1843.
Zhou, X., Gu, Z., Wu, Y., et al., Chin. Sci. Bull., 1993, vol. 38, pp. 175–184.
Sedov, V.P., Pretreatment of a C60 Fullerene Concentrate by Fractional Concentration, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2002, no. 2476.
Spitsyna N.G., Buravov, L.I., and Lobach, A.S., Zh. Anal. Khim., 1995, vol. 50, no. 6, pp. 673–676.
Isaacs, L., Wehsig, A., and Diederich, F., Helv. Chim. Acta, 1993, vol. 76, pp. 1231–1250.
US Patent 5 310 532.
US Patent 5 662 876.
US Patent 5 904 852.
Meier, M.S. and Selegue, J.P., J. Org. Chem., 1992, vol. 57, pp. 1924–1926.
RF Patent 2 224 714.
Grushko, Yu.S., Sedov, V.P., Alekseev, E.G., et al., Production of C60 Fullerene by Liquid Chromatography on Activated Carbon, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2004, no. 2556.
Khemani, K.C., Prato, M., and Wudl, F., J. Org. Chem., 1992, vol. 57, pp. 3254–3256.
Coustel, N., Bernier, P., Aznar, R., et al., J. Chem. Soc., Chem. Commun., 1992, pp. 1402–1403.
Nagota, K., Dejima, E., Kikuchi, Y., and Hashiguchi, M., Chem. Lett., 2005, vol. 34, pp. 178.
US Patent 5 711 927.
Troshin, P.A. and Lyubovskaya, R.N., Abstracts of Papers, 7th Biennial Int. Workshop “Fullerenes and Atomic Clusters,” St. Petersburg (Russia), June 25–July 1, 2005, p. 114.
Moskalev, P.N., Sedov, V.P., and Shilin, V.A., A Study of Adsorption Properties of Activated Carbons for C60 and C70 Fullerenes, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2006, no. 2695.
Grushko, Yu.S. and Sedov, V.P., Choice of a Technology for Production of Pure C70 Fullerene, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2005, no. 2617.
Sedov, V.P., Use of the Crystallization Method for Production of Pure C60 and C70 Fullerenes, Preprint of St. Petersburg Inst. of Nuclear Physics, Russ. Acad. Sci., Gatchina, 2005, no. 2417.
Murayama, H., Tomonoh, S., Alford, J.M., and Karpuk, M.E., Abstracts of Papers, 6th Biennial Int. Workshop “Fullerenes and Atomic Clusters,” St. Petersburg (Russia), June 30–July 4, 2003, p. 35.
Author information
Authors and Affiliations
Additional information
Original Russian Text © Yu.S. Grushko, V.P. Sedov, V.A. Shilin, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 3, pp. 450–457.
Rights and permissions
About this article
Cite this article
Grushko, Y.S., Sedov, V.P. & Shilin, V.A. Technology for manufacture of pure fullerenes C60, C70 and a concentrate of higher fullerenes. Russ J Appl Chem 80, 448–455 (2007). https://doi.org/10.1134/S1070427207030196
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/S1070427207030196