Skip to main content
SpringerLink
Log in

Evaporation of substances under kinetic or diffusion control in sublimation in a vacuum

  • Physicochemical Studies of Systems and Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

A diffusion-kinetic model of sublimation of substances in a vacuum is presented. The model defines two regions of the evaporation process depending on temperature: evaporation in the kinetic and diffusion control. The model was verified in experiments with benzoic acid and naphthalene by calculation of the sublimation rate of Zn, Co, V, and W, and by the known values of α.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Martinson, I.G. and Cherepkova, I.A., Zh. Prikl. Khim., 1996, vol. 69, no. 3, pp. 386–388.

    CAS  Google Scholar 

  2. Martinson, I.G. and Cherepkova, I.A., Zh. Prikl. Khim., 1996, vol. 69, no. 9, pp. 1446–1449.

    CAS  Google Scholar 

  3. Martinson, I.G., Zh. Prikl. Khim., 1998, vol. 71, no. 2, pp. 209–212.

    CAS  Google Scholar 

  4. Martinson, I.G., Zh. Fiz. Khim., 1998, vol. 72, no. 9, pp. 1698–1703.

    CAS  Google Scholar 

  5. Martinson, I.G., Zh. Fiz. Khim., 1996, vol. 70, no. 2, pp. 269–274.

    CAS  Google Scholar 

  6. Nesmeyanov, A.N., Davlenie para khimicheskikh elementov (Vapor Pressures of Chemical Elements), Moscow: Akad. Nauk SSSR, 1961.

    Google Scholar 

  7. Repinskii, S.M., Vvedenie v khimicheskuyu fiziku poverkhnosti tverdykh tel (Introduction to Chemical Physics of Soid Surfaces), Novosibirsk: Nauka, 1993, ch. 5.

    Google Scholar 

  8. Landolt, H. and Bornstein, R., Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik, 6 Aufl., Band 2, Teil 5, Berlin: Springer-Verlag, 1968, pp. 238–246, Erganzung pp. 395–396.

    Google Scholar 

  9. Chickos, James S. and Acree, William E., Jr., J. Phys. Chem. Ref. Data, 2002, no. 31(2), pp. 537–698.

    Article  CAS  Google Scholar 

  10. Lebedev, Yu.A. and Miroshnichenko, E.A., Termokhimiya paroobrazovaniya organicheskikh veshchestv: Teploty ispareniya, sublimatsii i davlenie nasyshchennogo para (Thermochemistry of Vaporization of Organic Substances: Heats of Evaporation and Sublimation and the Saturated Vapor Pressure), Moscow: Nauka, 1981.

    Google Scholar 

  11. Radchenko, L.G. and Kitaigorodskii, A.I., Zh. Fiz. Khim., 1974, no. 11, pp. 2702–2704.

  12. Krasulin, A.P., Kozyro, A.A., and Kabo, G.Ya., Zh. Prikl. Khim., 1987, vol. 54, no. 1, pp. 104–107.

    Google Scholar 

  13. Lebedev, D.P. and Perel’man, T.L., Teplo-i massoobmen v protsessakh sublimatsii v vakuume (Heat-and-Mass Exchange in Sublimation in a Vacuum), Moscow: Energiya, 1973.

    Google Scholar 

  14. Moelwyn-Hughes, E.A., Physical Chemistry, London: Pergamon, 1961.

    Google Scholar 

  15. Crystal Growth. Theory and Techniques, Goodman, C.H.L., Ed., London: Plenum, 1974, vol. 1.

    Google Scholar 

  16. Schlichting, H., Grenzschicht Theorie, Karlsruhe: Verlag, 1965.

    Google Scholar 

  17. Bretsznajder, S., Wlasnosci gazow i cieczy (Properties of Gases and Liquids), Warszawa: Naukowo-Techniczne, 1962.

    Google Scholar 

  18. Viktorov, M.M., Metody vychisleniya fiziko-khimicheskikh velichin i prikladnye raschety (Methods for Calculation of Physicochemical Quantities and Applied Calculations), Leningrad: Khimiya, 1977.

    Google Scholar 

  19. Reid, R.C., Prausnitz, J.M., and Sherwood, T.K., The Properties of Gases and Liquids, New York: McGraw-Hill, 1977.

    Google Scholar 

  20. Kucherov, R.Ya. and Rikenglaz, L.E., Zh. Eksp. Teor. Fiz., 1959, vol. 37, no. 1, pp. 125.

    Google Scholar 

  21. Kafarov, V.V. and Gorelik, A.M., Protsessy sublimatsii i desublimatsii v khimicheskoi tekhnologii: Obzornaya informatsiya (Sublimation and Desublimation Processes in Chemical Technology: A Review), Moscow: Khimiya, 1985.

    Google Scholar 

  22. Bogolyubov, N.A. and Masharov, S.I., Isparenie atomno-i magnitouporyadochennykh kristallov s defektami (Evaporation of Atomically and Magnetically Ordered Crystals with Defects), Novosibirsk: Nauka, 1989.

    Google Scholar 

  23. Andrievskii, R.A., Bairatashvili, I.A., and Soloev, Yu.I., Davlenie para i koeffitsient ispareniya bora (Vapor Pressure and Evaporation Coefficient of Boron), 1982, vol. 20, no. 5, pp. 862–865.

    CAS  Google Scholar 

  24. Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Goskhimizdat, 1962, vol. 1.

    Google Scholar 

  25. Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Sov. Entsiklopediya, 1990, vol. 2.

    Google Scholar 

  26. Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Sov. Entsiklopediya, 1988, vol. 1.

    Google Scholar 

  27. Gmelin Handbuch, 8 Aufl., Vanadium, Teil A — Lieferung 2, 1968, p. 437.

  28. Gmelin Handbuch of Inorganic Chemistry with Supplement, 1989, vol. A3, p. 146.

Download references

Author information

Authors and Affiliations

  1. Mendeleev Institute of Metrology, St. Petersburg, Russia

    I. G. Martinson

Authors
  1. I. G. Martinson
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © I.G. Martinson, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 8, pp. 1247–1253.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martinson, I.G. Evaporation of substances under kinetic or diffusion control in sublimation in a vacuum. Russ J Appl Chem 79, 1230–1237 (2006). https://doi.org/10.1134/S1070427206080040

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427206080040

Keywords

Search

Navigation