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Polysiloxane xerogels containing arch-fixed urea groups

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

A sol-gel procedure was suggested for preparing polysiloxane xerogels containing arch-fixed urea groups. The presence of these groups was confirmed by IR spectroscopy. The surface layer of the xerogels prepared exhibits enhanced hydrolytic stability in nonoxidizing acids.

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References

  1. Lisichkin, G.V., Fadeev, A.Yu., Serdan, A.A., et al., Khimiya privitykh poverkhnostnykh soedinenii (Chemistry of Grafted Surface Compounds), Moscow: Fizmat, 2003.

    Google Scholar 

  2. Tertykh, V.A. and Belyakova, L.A., Khimicheskie reaktsii s uchastiem poverkhnosti kremnezema (Chemical Reactions Involving Silica Surface), Kiev: Naukova Dumka, 1991.

    Google Scholar 

  3. Zaitsev, V.N., Kompleksoobrazuyushchie kremnezemy: sintez, stroenie privitogo sloya i khimiya poverkhnosti (Complexing Silicas: Synthesis, Structure of the Grafted Layer, and Surface Chemistry), Kharkov: Folio, 1997.

    Google Scholar 

  4. Khimiya poverkhnosti kremnezema (Silica Surface Chemistry), Chuiko, A.A., Ed., Kiev: Inst. Khimii Povkerhnosti, Nats. Akad. Nauk Ukr., 2001, vol. 1, parts 1, 2.

    Google Scholar 

  5. Vansant, E.F., Van Der Voort, P., and Vrancken, K.C., Characterization and Chemical Modification of the Silica Surface, Amsterdam: Elsevier, 1995.

    Google Scholar 

  6. Zub, Yu.L. and Parish, R.V., Stud. Surf. Sci. Catal., 1996, vol. 99, pp. 285–299.

    Article  CAS  Google Scholar 

  7. Zub, Yu.L. and Chuiko, A.A., Colloidal Silica: Fundamentals and Applications, Bergna, H.E., Ed., Washington, DC: Dekker, 2005, pp. 397–424.

    Google Scholar 

  8. Voronkov, M.G., Vlasova, N.N., and Pozhidaev, Yu.N., Appl. Organomet. Chem., 2000, vol. 14, pp. 287–303.

    Article  CAS  Google Scholar 

  9. Li, C., Glass, T., and Wilkes, G.L., J. Inorg. Organomet. Polym., 1999, vol. 9, pp. 79–106.

    Article  CAS  Google Scholar 

  10. Guizaro, C. and Lacan, P., New J. Chem., 1994, vol. 18, pp. 1097–1107.

    Google Scholar 

  11. Dubois, G., Coriu, R.J.P., Reye, C., et al., Chem. Commun., 1999, pp. 2283–2284.

  12. Voroshilova, O.I., Kiselev, A.V., and Nikitin, Yu.S., Kolloidn. Zh., 1980, vol. 42, no. 2, pp. 223–229.

    CAS  Google Scholar 

  13. Lin-Vien, D., Colthup, N.B., Fateley, W.G., and Grasselly, J.G., The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, San Diego, CA: Academic, 1991.

    Google Scholar 

  14. Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, New York: Wiley, 1957.

    Google Scholar 

  15. Finn, L.P. and Slinyakova, I.B., Kolloidn. Zh., 1975, vol. 37, no. 4, pp. 723–729.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    I. V. Mel’nik, N. V. Stolyarchuk, Yu. L. Zub & A. Dabrowski

  2. Maria Curie-Sklodowska University, Lublin, Poland

    I. V. Mel’nik, N. V. Stolyarchuk, Yu. L. Zub & A. Dabrowski

Authors
  1. I. V. Mel’nik
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  2. N. V. Stolyarchuk
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  3. Yu. L. Zub
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  4. A. Dabrowski
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Additional information

Original Russian Text © I.V. Mel’nik, N.V. Stolyarchuk, Yu.L. Zub, A. Dabrowski, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 6, pp. 992–997.

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Mel’nik, I.V., Stolyarchuk, N.V., Zub, Y.L. et al. Polysiloxane xerogels containing arch-fixed urea groups. Russ J Appl Chem 79, 981–986 (2006). https://doi.org/10.1134/S1070427206060206

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  • DOI: https://doi.org/10.1134/S1070427206060206

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