Abstract
The influence exerted by the nature of cation of a supporting electrolyte and by the current density on the electroreduction of oxygen to hydrogen peroxide in acid K2SO4 solutions (pH 0.9–1.4) in gas-diffusion hydrophobized carbon black electrodes with varied electrolyte porosity was studied.
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Mairanovskii, S.G., in Elektrosintez i bioelektrokhimiya: Progress elektrokhimii organicheskikh soedinenii (Electrosynthesis and Bioelectrochemistry: Advances in Electrochemistry of Organic Compounds), Moscow: Nauka, 1975, pp. 252–281.
Muraya Akira and Hori Yoshio, Bull. Chem. Soc. Jpn., 1991, vol. 64, no. 1, pp. 123–127.
Yorimitsu Kodama, Mitsutaka Imoto, Nobuaki Ohta, et al., J. Electroanal. Chem., 2001, vol. 507, no. 1, pp. 103–109.
Kolyagin, G.A. and Kornienko, V.L., Elektrokhimiya, 1996, vol. 32, no. 2, pp. 302–304.
Kolyagin, G.A. and Kornienko, V.L., Zh. Prikl. Khim., 1990, vol. 63, no. 7, pp. 1550–1554.
Fotadis, T., Kyriacou, G., Lambrou, C., and Hadjispyrou, S., J. Electroanal. Chem., 2000, vol. 480, nos. 1–2, pp. 249–254.
Fanigliulo, A. and Bozzini, B., J. Electroanal. Chem., 2002, vol. 530, no. 1, pp. 53–62.
Vicenzo, A. and Cavallotti, P.L., J. Appl. Electrochem., 2002, vol. 32, no. 7, pp. 743–753.
Gyenge, E.L. and Oloman, C.W., J. Appl. Electrochem., 2001, vol. 31, no. 2, pp. 233–243.
Gyenge, E.L. and Oloman, C.W., J. Appl. Electrochem., 2003, vol. 33, no. 8, pp. 655–663.
Gyenge, E.L. and Oloman, C.W., J. Appl. Electrochem., 2003, vol. 33, no. 8, pp. 665–674.
Anurova, A.I., Chernova, L.A., and Rotinyan, A.L., in Sbornik rabot po khimicheskim istochnikam toka (Coll. of Works on Chemical Power Cells), Leningrad: Energiya, 1973, issue 8, pp. 191–197.
Kornienko, V.L., Kolyagin, G.A., and Saltykov, Yu.V., Zh. Prikl. Khim., 1999, vol. 72, no. 3, pp. 353–361.
Kolyagin, G.A. and Kornienko, V.L., Khim. Inter. Ustoich. Razv., 2000, vol. 8, no. 6, pp. 803–807.
Kolyagin, G.A. and Kornienko, V.L., Zh. Prikl. Khim., 2003, vol. 76, no. 7, pp. 1103–1108.
Kublanovskii, V.S., Gorodyskii, A.V., Belinskii, V.N., and Glushchak, T.S., Kontsentratsionnye izmeneniya v prielektrodnykh sloyakh v protsesse elektroliza (Concentration Changes in Near-Electrode Layers in the Course of Electrolysis), Kiev: Naukova Dumka, 1978.
Kornienko, V.L. and Kolyagin, G.A., Elektrokhimiya, 2003, vol. 39, no. 12, pp. 1462–1470.
Brillas, E., Casado, J., and Caple, J.C., Water Res., 2000, vol. 34, no. 8, pp. 2253–2263.
Kolyagin, G.A. and Kornienko, V.L., Zh. Prikl. Khim., 1997, vol. 70, no. 3, pp. 500–502.
Baranov, A.P., Shteinberg, G.V., and Bagotskii, V.S., Elektrokhimiya, 1971, vol. 7, no. 3, pp. 387–390.
Kenova, T.A., Abolin, O.E., and Kornienko, V.L., Zh. Prikl. Khim., 1991, vol. 64, no. 3, pp. 670–673.
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Original Russian Text © G.A. Kolyagin, V.L. Kornienko, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 5, pp. 757–761.
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Kolyagin, G.A., Kornienko, V.L. Effect of trialkylammonium salts and current density on the electrosynthesis of hydrogen peroxide from oxygen in a gas-diffusion electrode in acid solutions. Russ J Appl Chem 79, 746–751 (2006). https://doi.org/10.1134/S1070427206050107
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DOI: https://doi.org/10.1134/S1070427206050107