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Comparative analysis of solubility in CuCl-MCl-H2O systems at 25°C (M+ = Li+, Cs+, NH +4 )

  • Physicochemical Studies of Systems and Processes
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Abstract

Solubility in the ternary system CuCl-NH4Cl-H2O at 25°C was determined by the method of isothermal lifting of oversaturation. A comparative analysis of solubility in this system and the previously studied systems CuCl-MCl-H2O (M+ = Li+, Na+, K+, Cs+) was made. The results obtained were interpreted in terms of competition between hydration, association, and complexation processes in water-salt systems.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    L. V. Stepakova, M. Yu. Skripkin & L. V. Chernykh

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  1. L. V. Stepakova
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  2. M. Yu. Skripkin
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  3. L. V. Chernykh
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Original Russian Text © L. V. Stepakova, M. Yu. Skripkin, L. V. Chernykh, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 4, pp. 560–564.

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Stepakova, L.V., Skripkin, M.Y. & Chernykh, L.V. Comparative analysis of solubility in CuCl-MCl-H2O systems at 25°C (M+ = Li+, Cs+, NH +4 ). Russ J Appl Chem 79, 549–554 (2006). https://doi.org/10.1134/S1070427206040082

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  • DOI: https://doi.org/10.1134/S1070427206040082

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