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Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines

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Abstract

Complexes of rhodium(II) acetate with 2H-azirines were obtained for the first time. The 1 : 2 complexes were characterized using 1H and 13C NMR, IR, and UV spectroscopy and high-resolution mass spectrometry. The structure of Rh2(OAc)4 complex with two 3-(4-methoxyphenyl)-2H-azirine molecules was studied by X-ray diffraction analysis. In crystal, the molecule of this complex belongs to the Ci point group.

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Funding

The work was carried out with the financial support of the Russian Science Foundation (grant 22-73-10184) using the equipment of the resource centers of St. Petersburg State University “Magnetic resonance research centre,” “X-ray diffraction research centre,” and “Chemical analysis and materials research centre.”

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  1. St. Petersburg University, 199034, St. Petersburg, Russia

    A. V. Grishin, I. P. Filippov & N. V. Rostovskii

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  1. A. V. Grishin
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  2. I. P. Filippov
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  3. N. V. Rostovskii
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Correspondence to N. V. Rostovskii.

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To the 300th Anniversary of the founding of St. Petersburg University

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Grishin, A.V., Filippov, I.P. & Rostovskii, N.V. Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines. Russ J Gen Chem 94 (Suppl 1), S47–S52 (2024). https://doi.org/10.1134/S107036322414007X

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