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Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone

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Abstract

Low-temperature (–90°C) ozonolysis of tris(trimethylsilyl)silane gave tris(trimethylsilyl)silanol and 1,1,1-trimethyl-2,2-bis(trimethylsiloxy)disilan-2-ol. The primary isotope effect in the reaction of tris(trimethylsilyl)silane with ozone at –90°C is equal to 5.5 and is consistent with the theoretical value calculated at the B3LYP/6-31+G(2d,p) level of theory assuming abstraction of H(D) from the Si–H(D) bond by ozone. Possible reaction mechanisms, namely radical, ionic, and ozone insertion into the Si–H bond, are discussed.

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ACKNOWLEDGMENTS

The author thanks S.L. Khursan and R.L. Safiullin (Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences) for helpful advices and fruitful discussion.

Funding

This study was performed in the framework of research schedule of the Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences (state registry no. 122031400201-0) using the equipment of the Chemistry joint center (Ufa Federal Research Center, Russian Academy of Sciences).

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  1. Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 450054, Ufa, Russia

    S. A. Grabovskiy

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Correspondence to S. A. Grabovskiy.

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Grabovskiy, S.A. Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone. Russ J Gen Chem 92, 1443–1448 (2022). https://doi.org/10.1134/S1070363222080114

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