Skip to main content
SpringerLink
Log in

The solubility and decomposition of ozone in solutions of sulfuric and perchloric acids in the temperature range from 25 to –70°C

  • Physical Chemistry
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

The solubility of ozone (O3) in 5 M solutions of H2SO4 or НСlO4 and in 18 M H2SO4 markedly increases as the temperature decreases from 25 to–70°C. In particular, the solubility coefficient of ozone (α = [Ο3]liq/[Ο3]gas) in 5 M H2SO4 increases in this temperature range from 0.13 to 1.47, the heat of solubility being 13.5 kJ/mol. At low temperature, the absorption band of ozone at 588 nm (ε = 4.5 L mol–1 cm–1) is detected. At T ≤–30°C, ozone virtually does not decompose in acid solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yoneda, N. and Olah, G.A., J. Am. Chem. Soc., 1977, vol. 99, no. 9, pp. 3113–3119.

    Article  CAS  Google Scholar 

  2. Kolenchin, N.F., Usp. Sovrem. Estestvozn., 2011, no. 3, pp. 78–79.

    Google Scholar 

  3. Krylova, L.N., Panin, V.V., Samoilovich, V.G., and Voronin, D.Yu., VI nauchno-prakticheskaya konferentsiya “Moskovskaya nauka—problemy i perspektivy” (VI Scientific and Practical Conference “Moscow Science—Problems and Prospects”) 2005, Moscow, 2005, pp. 416–425.

    Google Scholar 

  4. Ershov, B.G., Morozov, P.A., Gordeev, A.V., and Seliverstov, A.F., Khim. Tekhnol. Vody, 2009, vol. 31, no. 6, pp. 665–676.

    CAS  Google Scholar 

  5. Tyupalo, N.F., Lutsyk, A.I., Semenyuk, T.N., and Dmitruk, A.F., Dokl. Akad. Nauk SSSR, 1987, vol. 297, no. 3, pp. 624–627.

    CAS  Google Scholar 

  6. Levanov, A.V., Kuskov, I.V., Antipenko, E.E., and Lunin, V.V., Zh. Fiz. Khim., 2008, vol. 82, no. 7, pp. 1275–1281.

    Google Scholar 

  7. Speranza, M., J. Phys. Chem. A, 1998, vol. 102, no. 38, pp. 7535–7536.

    Article  CAS  Google Scholar 

  8. Bader, H. and Holgne, J., Ozone: Sci. Eng., 1982, vol. 4, no. 4, pp. 169–176.

    Article  CAS  Google Scholar 

  9. Panich, N.M. and Ershov, B.G., Zh. Fiz. Khim., 2008, vol. 82, no. 8, pp. 1423–1426.

    Google Scholar 

  10. Steinfeld, J.I., Adler-Golden, S.M., and Gallagher, J.W., J. Phys. Ref. Data, 1987, vol. 16, no. 4, pp. 911–951.

    Article  CAS  Google Scholar 

  11. Taube, H., Trans. Faraday Soc., 1957, vol. 53, pp. 656–665.

    Article  CAS  Google Scholar 

  12. Hart, E.J., Sehested, K., and Holcman, J., Anal. Chem., 1983, vol. 55, no. 1, pp. 46–49.

    Article  CAS  Google Scholar 

  13. Cacace, F. and Speranza, M., Science, 1994, vol. 265, no. 5169, pp. 208–209.

    Article  CAS  Google Scholar 

  14. Zakharov, I.I., Kolbasina, O.I., Semenyuk, T.N., Tyupalo, N.F., and Zhidomirov, G.M., Zh. Strukt. Khim., 1993, vol. 34, no. 2, pp. 28–32.

    CAS  Google Scholar 

  15. Aleksandrov, Yu.A., Tarunin, B.I., and Perepletchikov, M.L., Zh. Fiz. Khim., 1983, vol. 57, no. 10, pp. 2385–2397.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    B. G. Ershov & N. M. Panich

Authors
  1. B. G. Ershov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. M. Panich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. G. Ershov.

Additional information

Original Russian Text © B.G. Ershov, N.M. Panich, 2015, published in Doklady Akademii Nauk, 2015, Vol. 465, No. 2, pp. 190–193.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ershov, B.G., Panich, N.M. The solubility and decomposition of ozone in solutions of sulfuric and perchloric acids in the temperature range from 25 to –70°C. Dokl Phys Chem 465, 279–282 (2015). https://doi.org/10.1134/S0012501615110068

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501615110068

Keywords

Search

Navigation