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Synthesis, Characterization, and Luminescent Properties of a 3d Metal Coordination Polymer Based on Dicarboxylate Ligand and 1,10-Phenanthroline

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Abstract

Solvothermal reaction of MnSO4 with 2,2′-dithiodibenzoic acid (H2L) and 1,10-phenanthroline (phen) in ethanol/DMF/H2O has resulted in a novel manganese coordination polymer [Mn(L)(phen)(H2O)0.5]n (1). Compound 1 is built up of two chain structures derived from L2– ligands and Mn ions linked by coordination water molecules and the carboxylate groups of L2–. The L2– anions act as tridentate ligands bridging with Mn ions and generating a ladder-like structure comprised of left- and right-handed chains. In the solid state, compound 1 exhibits luminescence at 598 nm. In comparison with the free H2L ligand, compound 1 demonstrates 130 nm redshift, which can be attributed to charge transfer between ligands and metal ions. Compound 1 exhibits antiferromagnetic interactions between Mn ions.

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Funding

Scientific Research Fund Project of Liaoning Provincial Education Department (no. LJKZ0371).

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Authors and Affiliations

  1. School of Petrochemical Engineering, Liaoning Petrochemical University, 113001, Fushun, China

    Ying Wang, Lei Guan & Xin Wang

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  1. Ying Wang
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  2. Lei Guan
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Correspondence to Ying Wang.

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Wang, Y., Guan, L. & Wang, X. Synthesis, Characterization, and Luminescent Properties of a 3d Metal Coordination Polymer Based on Dicarboxylate Ligand and 1,10-Phenanthroline. Russ J Gen Chem 92, 1115–1120 (2022). https://doi.org/10.1134/S107036322206024X

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