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A New Method for the Synthesis of Tetraorganylphosphonium Arenesulfonates [Ph3PR1][OSO2R2]

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Abstract

The interaction of equimolar amounts of tetraorganylphosphonium chlorides with naphthalene-1sulfonic, 2,5-dichlorobenzenesulfonic, 2,4-dinitrobenzenesulfonic, and 1-hydroxy-2,4-dinitronaphthalene-7-sulfonic acids in water has led to the formation of tetraorganylphosphonium arenesulfonates [Ph3PR1][OSO2R2]. The phosphorus atoms in the cations exhibit distorted tetrahedral coordination and arenesulfonate anions have their ordinary geometry with tetrahedral sulfur atom.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & E. S. Mekhanoshina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. E. S. Mekhanoshina
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Correspondence to V. V. Sharutin.

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Sharutin, V.V., Sharutina, O.K. & Mekhanoshina, E.S. A New Method for the Synthesis of Tetraorganylphosphonium Arenesulfonates [Ph3PR1][OSO2R2]. Russ J Gen Chem 92, 969–976 (2022). https://doi.org/10.1134/S1070363222060081

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