Abstract
This study summarizes the literature data on the synthesis and structure of coordination compounds of alkali and alkaline earth metals, a series of M(I), M(II) transition metals, and rare earth elements with solvent molecules and boron cluster anions and their derivatives as ligands. The considered group of compounds has been classified in view of the nature of the coordinating solvent molecules as well as the position of boron cluster anions and their derivatives in the inner coordination sphere of the metal or the outer sphere. It has been shown that boron cluster anions and their derivatives are coordinated by metal atoms along with the solvent molecules via the three-center two-electron bonds in the presence of the Pearson’s soft acid metals [copper(I), silver(II), and lead(II)], forming the coordination polyhedrons. The possibility of the formation of mixed-ligand complexes due to the completion of the metal coordination polyhedron with the BH groups of the boron cluster has been revealed for the nonclassical complex-forming metals during the thermal treatment of the aqua complexes or the complexes with alcohol molecules as ligands, [ML6][BnHn] (M = Ca, Mg, Co, and Ni).
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REFERENCES
Greenwood, N.N. and Earnshaw, A., Chemistry of the Elements, Oxford: Butterworth-Heinemann, 1997.
Grimes, R.N., Carboranes, London: Academic Press, 2016, p. 1058. https://doi.org/10.1016/B978-0-12-801894-1.09989-3
Boron Science: New Technologies and Applications, Hosmane, N.S., Ed., Boca Raton, Florida: CRC Press, 2012.
Boron-Based Compounds: Potential and Emerging Applications in Medicine, Hey-Hawkins, E. and Viñas, C., Eds., Teixidor. Glasgow, UK: John Wiley & Sons Ltd., 2018, p. 470. https://doi.org/10.1002/9781119275602
Sivaev, I.B. and Bregadze, V.I., Polyhedral Boron Hydrides in Use: Current Status and Perspectives, Hauppauge: Nova Science Publishers, 2009, p. 85.
King, R.B., Chem. Rev., 2001, vol. 101, no. 5, p. 1119. https://doi.org/10.1021/cr000442t
Chen, Z. and King, R.B., Chem. Rev., 2005, vol. 105, no. 10, p. 3613. https://doi.org/10.1021/cr0300892
Zhizhin, K.Yu., Zhdanov, A.P., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2010, vol. 55, no. 14, p. 2089. https://doi.org/10.1134/S0036023610140019
Sivaev, I.B., Prikaznov, A.V., and Naoufal, D., Coll. Czech. Chem. Commun., 2010, vol. 75, no. 11, p. 1149. https://doi.org/10.1135/cccc2010054
Sivaev, I.B., Russ. J. Inorg. Chem., 2019, vol. 64, no. 8, p. 955. https://doi.org/10.1134/S003602361908014X
Klyukin, I.N., Selivanov, N.A., Bykov, A.Y., Zhdanov, A.P., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 10, p. 1547. https://doi.org/10.1134/S0036023620100113
Nelyubin, A.V., Selivanov, N.A., Bykov, A.Y., Klyukin, I.N., Novikov, A.S., Zhdanov, A.P., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 6, p. 795. https://doi.org/10.1134/S0036023620060133
Nelyubin, A.V., Klyukin, I.N., Zhdanov, A.P., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2019, vol. 64, no. 14, p. 1750. https://doi.org/10.1134/S0036023619140043
Nelyubin, A.V., Klyukin, I.N., Zhdanov, A.P., Grigor’ev, M.S., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2019, vol. 64, no. 12, p. 1499. https://doi.org/10.1134/S003602361912012X
Shmal’ko, A.V. and Sivaev, I.B., Russ. J. Inorg. Chem., 2019, vol. 64, no. 14, p. 1726. https://doi.org/10.1134/S0036023619140067
Nelyubin, A.V., Klyukin, I.N., Zhdanov, A.P., Grigor’ev, M.S., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2021, vol. 66, no. 2, p. 139. https://doi.org/10.1134/S0036023621020133
Avdeeva, V.V., Malinina, E.A., Zhizhin, K.Y., and Kuznetsov, N.T., Russ. J. Coord. Chem., 2021, vol. 47, no. 8, p. 519. https://doi.org/10.1134/S1070328421080017
Malinina, E.A., Avdeeva, V.V., Goeva, L.V., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2010, vol. 55, no. 14, p. 2148. https://doi.org/10.1134/S0036023610140032
Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2017, vol. 62, no. 13, p. 1673. https://doi.org/10.1134/S0036023617130022
Korolenko, S.E., Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2021, vol. 66, no. 9, p. 1350. https://doi.org/10.1134/S0036023621090047
Sivaev, I.B., Russ. J. Inorg. Chem., 2021, vol. 66, no. 9, p. 1289. https://doi.org/10.1134/S0036023621090151
Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 3, p. 335. https://doi.org/10.1134/S003602362003002X
Avdeeva, V.V., Polyakova, I.N., Vologzhanina, A.V., Malinina, E.A., Zhizhin, K.Yu., and Kuznetsov, N.T., Polyhedron, 2017, vol. 123, p. 396. https://doi.org/10.1016/j.poly.2016.12.009
Avdeeva, V.V., Vologzhanina, A.V., Malinina, E.A., and Kuznetsov, N.T., Crystals., 2019, vol. 9, no. 7, p. 330. https://doi.org/10.3390/cryst9070330
Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Polyhedron, 2016, vol. 105, p. 205. https://doi.org/10.1016/j.poly.2015.11.049
Avdeeva, V.V., Buzin, M.I., Malinina, E.A., Kuznetsov, N.T., and Vologzhanina, A.V., CrystEngComm., 2015, vol. 17, no. 46, p. 8870. https://doi.org/10.1039/c5ce00859j
Avdeeva, V.V., Buzin, M.I., Dmitrienko, A.O., Dorovatovskii, P.V., Malinina, E.A., Kuznetsov, N.T., Voronova, E.D., Zubavichus, Y.V., and Vologzhanina, A.V., Chem. Eur. J., 2017, vol. 23, no. 66, p. 16819. https://doi.org/10.1002/chem.201703285
Malinina, E.A., Avdeeva, V.V., Korolenko, S.E., Nefedov, S.E., Goeva, L.V., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 9, p. 1343. https://doi.org/10.1134/S0036023620090119
Kravchenko, E.A., Gippius, A.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 4, p. 546. https://doi.org/10.1134/S0036023620040105
Kravchenko, E.A., Gippius, A.A., Vologzhanina, A.V., Avdeeva, V.V., Malinina, E.A., Ulitin, E.O., and Kuznetsov, N.T., Polyhedron, 2016, vol. 117, p. 561. https://doi.org/10.1016/j.poly.2016.06.016
Avdeeva, V.V., Malinina, E.A., Zhizhin, K.Y., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 4, p. 514. https://doi.org/10.1134/S0036023620040026
Goeva, L.V., Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2018, vol. 63, no. 8, p. 1050. https://doi.org/10.1134/S0036023618080089
Matveev, E.Y., Novikov, I.V., Kubasov, A.S., Retivov, V.M., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2021, vol. 66, no. 2, p. 187. https://doi.org/10.1134/S0036023621020121
Malinina, E.A., Korolenko, S.E., Zhdanov, A.P., Avdeeva, V.V., Privalov, V.I., and Kuznetsov, N.T., J. Cluster Sci., 2021, vol. 32, p. 755. https://doi.org/10.1007/s10876-020-01840-5
Agafonov, A.V., Vinnitskii, D.M., Solntsev, K.A., Kuznetsov, N.T., Mikoyan, Z.N., and Ryurikov, V.F., Zh. Neorg. Khim., 1985, vol. 30, no. 2, p. 355.
Vinnitskii, D.M., Kuznetsov, I.Yu., Solntsev, K.A., and Kuznetsov, N.T., Zh. Neorg. Khim., 1987, vol. 32, no. 12, p. 3268.
Klimchuk, G.S. and Mustyasa, V.N., Abstract of Papers, IV All-Union Conf. on Hybrides Chemistry, Dushanbe., 1987, p. 44.
Kuznetsov, N.T., Zemskova, L.A., and Goeva, L.V., Coord. Khim., 1981, vol. 7, no. 2, p. 232.
Zimmermann, L.W. and Schleid, Th., Z. Kristallogr., 2013, vol. 228, no. 10, p. 558. https://doi.org/10.1524/zkri.2013.1634
Kuznetsov, N.T., Solntsev, K.A., and Klimchuk, G.S., Izv. AN SSSR. Neorg. Mater., 1978, vol. 14, no. 11, p. 2013.
Uspenskaya, S.M., Solntsev, K.A., and Kuznetsov, N.T., Zh. Strukt. Khim., 1975, vol. 16, no. 3, p. 482.
Solntsev, K.A., Kuznetsov, N.T., and Ponomarev, V.I., Dokl. AN SSSR, 1976, vol. 228, no. 4, p. 853.
Kuznetsov, N.T. and Klimchuk, G.S., Zh. Neorg. Khim., 1971, vol. 16, no. 5, p. 1218.
Solntsev, K.Α., Kuznetsov, N.T., and Ponomarev, V.I., Izv. AN SSSR. Neorg. Mater., 1976, vol. 12, no. 6, p. 1044.
Solntsev, Κ.Α., Kuznetsov, N.T., Rannev, Kh.V., and Zavodnik, V.E., Dokl. AN SSSR, 1977, vol. 232, no. 6, p. 1366.
Muetterties, E.L., Baltnis, J.H., Chia, Y.T., Knoth, W.N., and Miller, H.C., Inorg. Chem., 1964, vol. 3, no. 3, p. 444. https://doi.org/10.1021/ic50013a030
Solntsev, K.A., Kuznetsov, N.T., and Rannev, N.V., Dokl. AN SSSR., 1973, vol. 221, no. 6, p. 1378.
Tiritiris, I. and Schleid, T., Z. anorg. allg. Chem., 2002, vol. 628, p. 1411. https://doi.org/10.1002/1521-3749(200206)628:6<1411::AID-ZAAC1411>3.0.CO;2-X
Tiritiris, I. and Schleid, T., Z. anorg. allg. Chem., 2005, vol. 631, p. 1593. https://doi.org/10.1002/zaac.200500093
Tiritiris, I. and Schleid, T., Z. anorg. allg. Chem., 2004, vol. 630, p. 541. https://doi.org/10.1002/zaac.200300416
Tiritiris, I., Van, Ng.-D., and Schleid, T., Z. anorg. allg. Chem., 2004, vol. 630, p. 1763. https://doi.org/10.1002/zaac.200470138
Van, Ng.-D., PhD Thesis, Stuttgart, 2009.
Kuznetsov, N.T., Zemskova, L.Α., Alikhanova, Z.Μ., and Ippolitov, Ε.G., Zh. Neorg. Khim., 1981, vol. 26, no. 5, p. 1331.
Mikhailov, Yu.N., Kanishcheva A.S, Zemskova, L.A., Mistryukov, V.E., Kuznetsov, N.T., and Solntsev, K.A., Zh. Neorg. Khim., 1982, vol. 27, no. 9, p. 2343.
Kanaeva, O.A. and Kuznetsov, N.T., Trudy MITKhT, 1972, vol. 2, no. 2, p. 21.
Tiritiris, I. and Schleid, T., Z. anorg. allg. Chem., 2007, vol. 634, p. 317. https://doi.org/10.1002/zaac.200700399
Jørgensen, M., Zhou, W., Wu, H., Udovic, T.J., Paskevicius, M., Černý, R., and Jensen, T.R., Inorg. Chem., 2021, vol. 60, no. 15, p. 10943. https://doi.org/10.1021/acs.inorgchem.1c00594
Tiritiris, I., Van, Ng.-D., and Schleid, T., Z. anorg. allg. Chem., 2011, vol. 637, p. 682. https://doi.org/10.1002/zaac.201000457
Didelot, E., Sadikin, Y., Łodzian, Zb., and Černý, R., Solid State Sci., 2019, vol. 90, p. 86. https://doi.org/10.1016/j.solidstatesciences.2019.02.005
Kleeberg, F.M. and Schleid, T., Z. Kristallogr., 2017, suppl. 37, p. 107.
Bareiß, K. and Schleid, T., Z. Kristallogr., 2019, suppl. 39, p. 87.
Kuznetsov, N.T., Zemskova, L.Α., and Ippolitov, Ε.G., Zh. Neorg. Khim., 1981, vol. 26, no. 7, p. 1862.
Malinina, E.A., Korolenko, S.E., Kubasov, A.S., Buzanov, G.A., Golubev, A.V., Goeva, L.V., Simonenko, N.P., Avdeeva, V.V., and Kuznetsov, N.T., J. Solid State Chem., 2021, vol. 302, p. 122413. https://doi.org/10.1016/j.jssc.2021.122413
Kleeberg, F.M., Dinnebier, R.E., and Schleid, T., Inorg. Chim. Acta, 2017, vol. 467, p. 147. https://doi.org/10.1016/j.ica.2017.07.066
Lacroix, M.R., Bukovsky, E.V., Lozinšek, M., Folsom, T.C., Newell, B.S., Liu, Y., Peryshkov, D.V., and Strauss, S.H., Inorg. Chem., 2018, vol. 57, no. 23, p. 14983. https://doi.org/10.1021/acs.inorgchem.8b02786
Didelot, E., Łodziana, Z., Murgia, F., and Černý, R., Crystals, 2019, vol. 9, no. 7, p. 372. https://doi.org/10.3390/cryst9070372
Avdeeva, V.V., Polyakova, I.N., Goeva, L.V., Buzanov, G.A., Generalova, N.B., Malinina, E.A., Zhizhin, K.Y., Kuznetsov, N.T., and Vologzhanina, A.V., Russ. J. Inorg. Chem., 2016, vol. 61, no. 9, p. 1125. https://doi.org/10.1134/S0036023616090023
Avdeeva, V.V., Polyakova, I.N., Goeva, L.V., Buzanov, G.A., Malinina, E.A., and Kuznetsov, N.T., Inorg. Chim. Acta, 2016, vol. 451, p. 129. https://doi.org/10.1016/j.ica.2016.07.016
Malinina, E.A., Goeva, L.V., Buzanov, G.A., Avdeeva, V.V., Kuznetsov, N.T., and Retivov, V.M., Russ. J. Inorg. Chem., 2020, vol. 65, no. 1, p. 126. https://doi.org/10.1134/S0036023620010118
Malinina, E.A., Korolenko, S.E., Goeva, L.V., Buzanov, G.A., Avdeeva, V.V., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2018, vol. 63, no. 12, p. 1552. https://doi.org/10.1134/S0036023618120148
Korolenko, S.E., Goeva, L.V., Kubasov, A.S., Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 6, p. 846. https://doi.org/10.1134/S0036023620060091
Avdeeva, V.V., Vologzhanina, A.V., Ugolkova, E.A., Minin, V.V., Malinina, E.A., and Kuznetsov, N.T., J. Solid State Chem., 2021, vol. 296, p. 121989. https://doi.org/10.1016/j.jssc.2021.121989
Kuznetsov, N.T. and Zemskova, L.A., Zh. Neorg. Khim., 1982, vol. 27, no. 5, p. 1320
Korolenko, S.E., Zhuravlev, K.P., Tsaryuk, V.I., Kubasov, A.S., Avdeeva, V.V., Malinina, E.A., Burlov, A.S., Divaeva L.N, Zhizhin, K.Yu., and Kuznetsov, N.T., J. Lumin., 2021, vol. 237, p. 118156. https://doi.org/10.1016/j.jlumin.2021.118156
Korolenko, S.E., Kubasov, A.S., Goeva, L.V., Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Inorg. Chim. Acta, 2021, vol. 520, p. 120315. https://doi.org/10.1016/j.ica.2021.120315
Korolenko, S.E., Kubasov, A.S., Goeva, L.V., Avdeeva, V.V., Malinina, E.A., and Kuznetsov, N.T., Inorg. Chim. Acta, 2021, vol. 527, p. 120587. https://doi.org/10.1016/j.ica.2021.120587
Milutka, M.S., Burlov, A.S., Vlasenko, V.G., Koschienko, Yu.V., Makarovs, N.I., Metelitsa, A.V., Korshuniva, E.V., Trigub, A.L., Zubenko, A.A., and Klimenko, A.I., Russ. J. Gen. Chem., 2021, vol. 91, p. 1706. https://doi.org/10.1134/S1070363221090140
Zakharova, I.A., Kuznetsov, N.Т., and Gaft, Yu.L., Inorg. Chim. Acta, 1978, vol. 28, p. 271. https://doi.org/10.1016/S0020-1693(00)87446-0
Musgrave, R.A., Hailes, R.L.N., Schäfer, A., Russell, A.D., Gates, P.J., and Manners, I., Dalton Trans., 2018, vol. 47, p. 2759. https://doi.org/10.1039/C7DT04593J
Peryshkov, D.V. and Strauss, S.H., Inorg. Chem., 2017, vol. 56, no. 7, p. 4072. https://doi.org/10.1021/acs.inorgchem.7b00051
Zhang, Y., Liu, J., and Duttwyler, S., Eur. J. Inorg. Chem., 2015, p. 5158. https://doi.org/10.1002/ejic.201501009
Malinina, E.A., Zhizhin, K.Yu., Mustyatsa, V.N., Goeva, L.V., Polyakova, I.N., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2003, vol. 48, no. 7, p. 993.
Avdeeva, V.V., Malinina, E.A., Churakov, A.V., Polyakova, I.N., and Kuznetsov, N.T., Polyhedron, 2019, vol. 169, p. 144. https://doi.org/10.1016/j.poly.2019.05.018
Malinina, E.A., Drozdova, V.V., Mustyatsa, V.N., Goeva, L.V., Polyakova, I.N., Votinova, N.A., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2006, vol. 51, no. 11, p. 1723. https://doi.org/10.1134/S0036023606110076
Polyakova, I.N., Malinina, E.A., Drozdova, V.V., and Kuznetsov, N.T., Crystallography Reports, 2008, vol. 53, no. 2, p. 253. https://doi.org/10.1007/s11445-008-2013-3
Volkov, O., Hu, Ch., and Paetzold, P., Z. anorg. allg. Chem., 2005, vol. 631, p. 1107. https://doi.org/10.1002/zaac.200400518
Ivanov, S.V., Ivanova, S.I., Miller, S.M., Anderson, O.P., Solntsev, K.A., and Strauss, S.H., Inorg. Chem., 1996, vol. 35, no. 24, p. 6914. https://doi.org/10.1021/ic961043c
Malischewski, M., Peryshkov, D.V., Bukovsky, E.V., Seppelt, K., and Strauss, S.H., Inorg. Chem., 2016, vol. 55, no. 23, p. 12254. https://doi.org/10.1021/acs.inorgchem.6b01980
Avdeeva, V.V., Buzanov, G.A., Malinina, E.A., Kuznetsov, N.T., and Vologzhanina, A.V., Crystals, 2020, vol. 10, p. 389. https://doi.org/10.3390/cryst10050389
Saleh, M., Powell, D.R., and Wehmschulte, R.J., Inorg. Chem., 2016, vol. 55, no. 20, p. 10617. https://doi.org/10.1021/acs.inorgchem.6b01867
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Avdeeva, V.V., Korolenko, S.E., Malinina, E.A. et al. Solvent Molecules as Ligands in Coordination Compounds of Metals with Boron Cluster Anions and Their Derivatives (A Review). Russ J Gen Chem 92, 393–417 (2022). https://doi.org/10.1134/S1070363222030070
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DOI: https://doi.org/10.1134/S1070363222030070