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Solvothermal Syntheses, Crystal Structure, and Properties of Two Th(IV) Complexes Based on Diacylhydrazone Ligand

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Abstract

Two Th(IV) complexes have been synthesized by a “one-pot” method. The complexes have been characterized by IR, NMR and mass spectra, elemental analysis, and single crystal X-ray diffraction. Structural analysis indicates that Th(IV) in both complexes is twelve-coordinated. A one-dimensional infinite chain structure is formed in C1 via π–π stacking of benzene. According to TGA, the complexes are stable below 200°C. UV-Vis and fluorescence spectra of complexes have been recorded. Quantum chemical calculations of the complexes have been carried out.

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Notes

  1. CCDC: 2077406, C1; 2077407, C2 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via the Cambridge Crystallographic Data Centre http://www.ccdc.cam.ac.uk/conts/retrieving.html (or from the CCDC, 12 Union Road, Cambridge CB21EZ, UK; Fax: +44 1223 336033; E-mail: deposit@ccdc.cam.ac.uk).

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Funding

This work was supported by the foundation of Hunan provincial engineering research centre for uranium exploration technology (no. YK20K03).

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Authors and Affiliations

  1. Hengyang Normal University, Hengyang, 421008, Hunan, China

    Yuxing Tan, Yanliang Tan & Wujiu Jiang

  2. Nuclear Bureau of Hunan Province Nuclear Industry Brigade 306, Hengyang, 421008, Hunan, China

    Xiaolong Nan

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  1. Yuxing Tan
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Correspondence to Wujiu Jiang.

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Tan, Y., Nan, X., Tan, Y. et al. Solvothermal Syntheses, Crystal Structure, and Properties of Two Th(IV) Complexes Based on Diacylhydrazone Ligand. Russ J Gen Chem 91, 2267–2271 (2021). https://doi.org/10.1134/S107036322111013X

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