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Methylene Components Exchange in the Reaction of Cyanoacetohydrazide with 2-Amino-4-arylbuta-1,3-diene-1,1,3-tricarbonitriles

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Abstract

2-Amino-4-arylbuta-1,3-diene-1,1,3-tricarbonitriles obtained by Knoevenagel condensation between aldehydes and malononitrile dimer reacted with cyanoacetohydrazide in the presence of bases to afford N’-arylidene-2-cyanoacethydrazides instead of the expected heterocyclization products of the pyridine series.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the Scientific and Educational Center “Diagnostics of the Structure and Properties of Nanomaterials” and the Ecological Analytical Center of the Kuban State University.

Funding

This work was financially supported by the Russian Foundation for Basic Research and the Administration of the Krasnodar Territory (project no. 20-43-235002 “r_Master_Krasnodar,” as well as the Ministry of Education and Science of the Russian Federation (topic 0795-2020-0031).

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    A. G. Levchenko, P. G. Dahno, A. R. Chikava & V. V. Dotsenko

  2. North Caucasus Federal University, 355009, Stavropol, Russia

    V. V. Dotsenko, N. A. Aksenov & I. V. Aksenova

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  1. A. G. Levchenko
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  2. P. G. Dahno
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Correspondence to V. V. Dotsenko.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 11, pp. 1650–1657 https://doi.org/10.31857/S0044460X21110020.

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Levchenko, A.G., Dahno, P.G., Chikava, A.R. et al. Methylene Components Exchange in the Reaction of Cyanoacetohydrazide with 2-Amino-4-arylbuta-1,3-diene-1,1,3-tricarbonitriles. Russ J Gen Chem 91, 2129–2135 (2021). https://doi.org/10.1134/S1070363221110025

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