Skip to main content
SpringerLink
Log in

Special Features of Formation of Inclusion Complexes of Mono-Substituted β-Cyclodextrin Derivatives

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

In an attempt to obtain inclusion compounds of a series of mono derivatives of β-cyclodextrin containing ester and ether bonds with certain aromatic and aliphatic carboxylic acids, unexpected guest-host inclusion compounds have been obtained, presumably due to the preliminary inclusion of the guest into the of β-cyclodextrin cavity. Structure and composition of the inclusion complexes have been confirmed by 1H and 13C NMR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Scheme
Scheme
Scheme

Similar content being viewed by others

Notes

  1. The prime marks the С6 atoms of carbohydrate fragments of cyclodextrin bearing the substituent.

  2. We have earlier obtained and characterized the inclusion complexes 6, 7, 16, and 14 of unsubstituted β-cyclodextrin 1 with benzoic acid 4, 2-(4-isobutylphenyl)propionic acid 5, and nicotinic acid 11 (with the same 1 : 2 ratio) [18]; however, they have been obtained via the direct interaction of β-cyclodextrin 1 with the corresponding guest.

  3. 1Н and 13С NMR spectra as well as melting points (decomp.) of inclusion compounds 6, 13, and 15 coincided with the earlier reported data [16–18].

REFERENCES

  1. Cyclodextrin Fundamentals, Reactivity and Analysis. Inserious of Environmental Chemistry for a Sustainable World, Lichtfouse, Е., Fourmentin, S., and Crini, G., Eds., Springer, 2018. 262 р. https://doi.org/10.1007/978-3-319-76159-6

  2. Khan, A.R., Forgo, P., Stine, K.J., and D’Souza, V.T., Chem. Rev., 1998, vol. 98, no. 5, p. 1977.

    Article  CAS  Google Scholar 

  3. Shipilov, D.A., Kurochkina, G.I., Rasadkina, E.N., Vasyanina, L.K., Grachev, M.K., and Soboleva, N.O., Russ. J. Gen. Chem., 2015, vol. 85, no. 11, p. 2605. https://doi.org/10.1134/S107036321511016X

    Article  CAS  Google Scholar 

  4. Kutyasheva, N.V., Kurochkina, G.I., Solomatin, E.A., and Grachev, M.K., Russ. J. Org. Chem., 2021, vol. 57, no. 1, p. 92. https://doi.org/10.31857/S0514749221010146

    Article  Google Scholar 

  5. Glazyrin, A.E., Kurochkina, G.I., Crachev, M.K., and Nifant’ev, E.E., Mendeleev Commun., 2001, no. 6, p. 218. https://doi.org/10.1070/MC2001v011n06ABEH001487

    Article  CAS  Google Scholar 

  6. Grachev, M.K., Glazyrin, A.E., Kurochkina, G.I., and Nifant’ev, E.E., Russ. J. Gen. Chem., 2004, vol. 74, p. 808.

    Article  CAS  Google Scholar 

  7. Glazyrin, A.E., Syrtsev, A.N., Kurochkina, G.I., Kononov, L.O., Crachev, M.K., and Nifant’ev, E.E., Russ. Chem. Bull., 2003, vol. 52, p. 237. https://doi.org/10.1023/A:1022485407440

    Article  CAS  Google Scholar 

  8. Grachev, M.K., Russ. Chem. Rev., 2013, vol. 82, p. 1034. https://doi.org/10.1070/RC2013v082n11ABEH004381

    Article  CAS  Google Scholar 

  9. Shipilov, D.A., Kurochkina, G.I., Batalova, T.A., and Grachev, M.K., Russ. J. Org. Chem., 2015, vol. 51, no. 10, p. 1395. https://doi.org/10.1134/S1070428015100061

    Article  CAS  Google Scholar 

  10. Grachev, M.K., Edunov, A.V., Kurochkina, G.I., Soboleva, N.O., Vasyanina, L.K., and Nifant’ev, E.E., Russ. Chem. Bull., 2012, vol. 61, no. 1, p. 181. https://doi.org/10.1007/S11172-012-

    Article  CAS  Google Scholar 

  11. Coates, J.H., Easton, C.J., Fryer, N.L., and Lincoln, S.F., Chem. Lett., 1994, p. 1153. https://doi.org/10.1246/cl.1994.1153

  12. Wood, D.J., Hruska, F.E., and Saenger, W., J. Am. Chem. Soc., 1977, vol. 99, p. 1735. https://doi.org/10.1021/ja00448a009

    Article  CAS  Google Scholar 

  13. Smith, C.Z. and Utley, J.H.P., Chem. Commun., 1981, p. 492. https://doi.org/10.1039/C39810000492

  14. Schneider, H.-J., Hacket, F., and Rüdiger, V., Chem. Rev., 1998, vol. 98, p. 1755. https://doi.org/10.1021/cr970019t

    Article  CAS  PubMed  Google Scholar 

  15. Stepanov, A.A., Volodin, Yu.Yu., Grachev, M.K., Kurochkina, G.I., Syrtsev, A.N., and Grinberg, V.A., Russ. J. Electrochem., 2002, vol. 38, no. 12, p. 1346. https://doi.org/10.1023/A:1021629007747

    Article  CAS  Google Scholar 

  16. Kurochkina, G.I., Kudryavtseva, N.A., Grachev, M.K., Lysenko, S.A., Vasyanina, L.K., and Nifant’ev, E.E., Russ. J. Gen. Chem., 2007, vol. 77, no. 3, p. 442. https://doi.org/10.1134/S1070363207030188

    Article  CAS  Google Scholar 

  17. Grachev, M.K., Senyushkina, I.A., Kurochkina, G.I., Lysenko, S.A., Vasyanina, L.K., and Nifant’ev, E.E., Russ. J. Org. Chem., 2010, vol. 46, no. 10, p. 1506. https://doi.org/10.1134/S1070428010100118

    Article  CAS  Google Scholar 

  18. Senyushkina, I.A., Kurochkina, G.I., Grachev, M.K., Grinberg, V.A., Batalova, T.A., and Nifant’ev, E.E., Russ. J. Gen. Chem., 2009, vol. 79, no. 6, p. 1167. https://doi.org/10.1134/S1070363209060231

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State Pedagogical University, Institute of Biology and Chemistry, 119021, Moscow, Russia

    N. V. Kutyasheva, G. I. Kurochkina, V. V. Glushko & M. K. Grachev

Authors
  1. N. V. Kutyasheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. I. Kurochkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Glushko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. K. Grachev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Kutyasheva.

Ethics declarations

No conflict of interest was declared by the authors.

Additional information

Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 6, pp. 959–965 https://doi.org/10.31857/S0044460X21060135.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kutyasheva, N.V., Kurochkina, G.I., Glushko, V.V. et al. Special Features of Formation of Inclusion Complexes of Mono-Substituted β-Cyclodextrin Derivatives. Russ J Gen Chem 91, 1070–1074 (2021). https://doi.org/10.1134/S107036322106013X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036322106013X

Keywords:

Search

Navigation