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Hydrosilylation of Allylgermanes

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Abstract

The hydrosilylation reactions of allylgermanes R3GeAll (R3 = Cl3, Me3) in the presence of a platinum catalyst (Karstedt catalyst) with methylchlorohydridesilanes MenCl3–nSiH (n = 0–2) and 1,1,3,3-tetramethyldisiloxane have been studied. It was found that only 1,3-adducts are formed. In some cases, the replacement of only one methyl group at silicon with Cl (or vice versa, Cl for methyl group) leads not only to a decrease in the yields of the products obtained, but to a complete absence of reaction. A possible route of the studied reactions is proposed. The identification of the synthesized compounds was carried out using the methods of gas-liquid chromatography, 1H NMR spectroscopy and chromatography-mass spectrometry.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelement Compounds, 105118, Moscow, Russia

    V. G. Lakhtin, D. A. Efimenko, A. M. Filippov, T. I. Shulyatieva, I. B. Sokolskaya, I. A. Semyashkina, N. G. Komalenkova & P. A. Storozhenko

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  1. V. G. Lakhtin
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  2. D. A. Efimenko
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  3. A. M. Filippov
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  4. T. I. Shulyatieva
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  5. I. B. Sokolskaya
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  6. I. A. Semyashkina
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Correspondence to V. G. Lakhtin.

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Lakhtin, V.G., Efimenko, D.A., Filippov, A.M. et al. Hydrosilylation of Allylgermanes. Russ J Gen Chem 91, 77–84 (2021). https://doi.org/10.1134/S1070363221010084

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  • DOI: https://doi.org/10.1134/S1070363221010084

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