Skip to main content
SpringerLink
Log in

Ionization and Complexing Properties of Hyperbranched Polyester Poly[3-(2-aminoethyl)amino)]propionate

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Syntheses of a polydentate ligand based on the second-generation hyperbranched polyester containing 3-(2-aminoethyl)amino]propionate groups and its metal complex with copper(II) ions have been elaborated. In view of the IR, electronic absorption, and EPR spectroscopy data, it has been suggested that the coordination sites in the metal-polymer complex are paramagnetic sites with the CuN4Solv2 or CuN2O2Solv2 composition (Solv = H2O, DMSO).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Scheme
Scheme
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Uflyand, I.E. and Dzhardimalieva, G.I., J. Coord. Chem., 2018, vol. 71, no. 9, p. 1272. https://doi.org/10.1080/00958972.2018.1465567

    Article  CAS  Google Scholar 

  2. Gao, С. and Yan, D., Prog. Polym. Sci., 2004, vol. 29, p. 183. https://doi.org/10.1016/j.progpolymsci.2003.12.002

    Article  CAS  Google Scholar 

  3. Yates, C.R. and Hayes, W., Eur. Polym. J., 2004, vol. 40, p. 1257. https://doi.org/10.1016/j.eurpolymj.2004.02.007

    Article  CAS  Google Scholar 

  4. Diallo, M., Balogh, L., Shafagati, A., Johnson, I.H., Goddard, W.A., and Tomalia, D.A., Environ. Sci. Technol., 1999, vol. 33, no. 5, p. 820. https://doi.org/10.1021/es980521a

    Article  CAS  Google Scholar 

  5. Jang, W.-D., Kamruzzaman Selim, K.M., Lee, C.-H., and Kang, I.-K., Prog. Polym. Sci., 2009, vol. 34, p. 1. https://doi.org/10.1016/j.progpolymsci.2008.08.003

    Article  CAS  Google Scholar 

  6. Manoj, E., Kurup, M.R.P., and Punnoose, A., Spectrochim. Acta. (A), 2009, vol. 72, no. 3, p. 474. https://doi.org/10.1016/j.saa.2008.10.030

    Article  CAS  Google Scholar 

  7. Wang, S.J., Brechbiel, M., and Wiener, E.C., Invest. Radiol., 2003, vol. 38, no. 10, p. 662. https://doi.org/10.1097/01.rli.0000084887.47427.75

    Article  CAS  PubMed  Google Scholar 

  8. Labieniec, M. and Watala, C., Cent. Eur. J. Biol., 2009, vol. 4, no. 4, p. 434. https://doi.org/10.2478/s11535-009-0056-7

    Article  CAS  Google Scholar 

  9. Ottaviani, M.F., Montalti, F., Turro, N.I., and Tomalia, D.A., J. Phys. Chem. (B), 1997, vol. 101, no. 2, p. 158. https://doi.org/10.1021/jp962857h

    Article  CAS  Google Scholar 

  10. Bosman, A.W., Schenning, A.P.H.J., Janssen, R.A.J., and Meijer, E.W., Chem. Ber. Recueil., 1997, vol. 130, p. 725. https://doi.org/10.1002/cber.19971300608

    Article  CAS  Google Scholar 

  11. Krot, K.A., Danil de Namor, A.F., Aguilar-Cornejo, A., and Nolan, K.B., Inorg. Chim. Acta, 2005, vol. 358, p. 3497. https://doi.org/10.1016/j.ica.2005.05.001

    Article  CAS  Google Scholar 

  12. Diallo, M.S., Christie, S., Swaminathan, P., Balogh, L., Shi, X., Um, W., Papelis, C., Goddard, W.A., and Jonson, J.H., Langmuir, 2004, vol. 20, no. 7, p. 2640. https://doi.org/10.1021/la036108k

    Article  CAS  PubMed  Google Scholar 

  13. Zhou, L., Russell, D.H., Zhao, M., and Crooks, R.M., Macromolecules, 2001, vol. 34, no. 11, p. 3567. https://doi.org/10.1021/ma001782j

    Article  CAS  Google Scholar 

  14. Ottaviani, M.F., Bossmann, S., Turro, N.J., and Tomalia, D.A., J. Am. Chem. Soc., 1994, vol. 116, no. 2, p. 661. https://doi.org/10.1021/ja00081a029

    Article  CAS  Google Scholar 

  15. Floriano, P.N., Noble, Schoonmaker, J.M., Poliakoff, E.D., McCarley, R.L., J. Am. Chem. Soc., 2001, vol. 123, no. 43, p. 10545. https://doi.org/10.1021/ja010549d

    Article  CAS  PubMed  Google Scholar 

  16. Mecke, A., Uppuluri, S., Sassanella, T.M., Lee, D.K., Ramamoorthy, A., Baker, J.R.Jr., Orr, B.G., and Banaszak Holl, M.M., Chem. Phys. Lipids, 2004, vol. 132, no. 1, p. 3. https://doi.org/10.1016/j.chemphyslip.2004.09.001

    Article  CAS  PubMed  Google Scholar 

  17. Kobayashi, H., Kawamato, S., Jo, S.K., Bryant, H.L.Jr., Brechbiel, M.W., and Star, R.A., Bioconjug. Chem., 2003, vol. 14, no. 2, p. 388. https://doi.org/10.1021/bc025633c

    Article  CAS  PubMed  Google Scholar 

  18. Inoue, K., Prog. Polym. Sci., 2000, vol. 25, no. 4, p. 453. https://doi.org/10.1016/S0079-6700(00)00011-3

    Article  CAS  Google Scholar 

  19. Žagar, E. and Žigon, M., Prog. Polym. Sci., 2011, vol. 36, no. 1, p. 53. https://doi.org/10.1016/j.progpolymsci.2010.08.004

    Article  CAS  Google Scholar 

  20. Нäußler, M., Dong, H., and Tang, B.Z., Inorganic and Organometallic Macromolecules: Desigh and Application, Springer Science+Business Media, LLC, 2008, p. 21. https://doi.org/10.1007/978-0-387-72947-3_2

  21. Zhong, Z., Song, Y., Engbersen, J.F.J., Lok, M.C., Hennink, W.E., and Feijen, J., J. Control Release, 2005, vol. 109, no. 1–3, p. 317. https://doi.org/10.1016/j.jconrel.2005.06.022

    Article  CAS  PubMed  Google Scholar 

  22. Reul, R., Nguyen, J., and Kissel, T., Biomaterials, 2009, vol. 30, no. 29, p. 5815. https://doi.org/10.1016/j.biomaterials.2009.06.057

    Article  CAS  PubMed  Google Scholar 

  23. Arote, R., Kim, T.H., Hwang, Y.K., Jiang, H.L., Nah, J.W., Cho, M.H., and Cho, C.S., Biomaterials, 2007, vol. 28, no. 4, p. 735. https://doi.org/10.1016/j.biomaterials.2006.09.028

    Article  CAS  PubMed  Google Scholar 

  24. Reul, R., Nguyen, J., Biela, A., Marxer, E., Bakowsky, U., Klebe, G., and Kissel, T., Int. J. Pharm., 2012, vol. 436, nos. 1–2, p. 97. https://doi.org/10.1016/j.ijpharm.2012.06.065

    Article  CAS  PubMed  Google Scholar 

  25. Kutyreva, M.P., Gataulina, A.R., Kutyrev, G.A., Ulakhovich, N.A., Newman, T., Khasanova, E.M., Bondar, O.V., Yurtaeva, S.V., Ziganshina, S.A., and Khaldeeva, E.V., Inorg. Chim. Acta, 2016, vol. 450, p. 101. https://doi.org/10.1016/j.ica.2016.04.013

    Article  CAS  Google Scholar 

  26. Khannanov, A.A., Kutyreva, М.P., Ulakhovich, N.A., Gataulina, А.R., Bondar, О.V., Zakharova, L.Y., and Kutyrev, G.A., Fluid Phase Equilibria, 2016, vol. 411, p. 93. https://doi.org/10.1016/j.fluid.2015.12.023

    Article  CAS  Google Scholar 

  27. Kutyreva, M.P., Usmanova, G.Sh., Ulakhovich, N.A., Medvedeva, O.I., Syakaev, V.V., and Ziganshina, S.A., Polym. Sci. (B), 2013, vol. 55, nos. 3–4, p. 201. https://doi.org/10.1134/S1560090413040052

    Article  CAS  Google Scholar 

  28. Gataulina, A.R., Khannanov, A.A., Malinovskikh, O.A., Bondar, O.V., Ulakhovich, N.A., and Kutyreva, M.P., Russ. J. Gen. Chem., 2013, vol. 83, no. 12, p. 2269. https://doi.org/10.1134/S1070363213120074

    Article  CAS  Google Scholar 

  29. Gataulina, A.R., Khasanova, E.M., Ulakhovich, N.A., Kutyrev, G.A., and Kutyreva, M.P., Russ. J. Gen. Chem., 2018, vol. 88, no. 9, p. 1874. https://doi.org/10.1134/S1070363218090189

    Article  CAS  Google Scholar 

  30. Kutyreva, M.P., Gataulina, A.R., Kutyrev, G.A., Nizamov, I.S., and Ulakhovich, N.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 7, p. 1535. https://doi.org/10.1134/S1070363211070206

    Article  CAS  Google Scholar 

  31. Bellamy, L.J., The Infrared Spectra of Complex Molecules Volume Two Advances in Infrared Group Frequencies, London: Methuen Inc., Chapman and Hall, 1980. https://doi.org/10.1007/978-94-011-6520-4

  32. Toroptseva, A.M., Belogorodskaya, K.V., and Bondarenko, V.M., Laboratornyi praktikum po khimii i tekhnologii vysokomolekulyarnykh soedinenii (Laboratory Workshop on Chemistry and Technology of High-Molecular Compounds), Leningrad: Khimiya, 1972, p. 127.

  33. Kutyreva, M.P., Ulakhovich, N.A., Sidorov, P.O., Kutyrev, G.A., Gataulina, A.R., and Salnikov, Yu.I., World Appl Sci. J., 2013, vol. 26, no. 7, p. 973. https://doi.org/10.5829/idosi.wasj.2013.26.07.13533

    Article  CAS  Google Scholar 

  34. Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, New York: John Wiley and Sons Inc., 1970. https://doi.org/10.1002/bbpc.19710750622

  35. Kacan, M., Turkyilmaz, M., Karabulut, F., Altun, O., and Baran, Y., Spectrochim. Acta (A), 2014, vol. 118, p. 572. https://doi.org/10.1016/j.saa.2013.09.031

    Article  CAS  Google Scholar 

  36. Basha, M.T., Alghanmi, R.M., Shehata, M.R., Abdel-and Rahman, L.H., J. Mol. Struct., 2019, vol. 1183, p. 298. https://doi.org/10.1016/j.molstruc.2019.02.001

    Article  CAS  Google Scholar 

  37. Lever, A.B.P., Inorganic Electronic Spectroscopy in Studies in Physical and Theoretical Chemistry, Amsterdam: Elsevier, 1984. 863 p. https://doi.org/10.1002/bbpc.19850890122

  38. Volchenskova, I.I., Teor. Eksp. Khim., 1973, vol. 9, no. 5, p. 627.

    CAS  Google Scholar 

  39. Rybak-Akimova, E.V., Nazarenko, A.Y., Chen, L., Krieger, P.W., Herrera, A.M., Tarasov, V.V., and Robinson, P.D., Inorg. Chim. Acta, 2001, vol. 324, nos. 1–2, p. 1. https://doi.org/10.1016/S0020-1693(01)00495-9

    Article  CAS  Google Scholar 

  40. Kokorin, A.I., Vengerova, N.A., Kirsh, Yu.E., and Zamaraev, K.I., Dokl. Akad. Nauk SSSR, 1972, vol. 202, no. 3, p. 597.

    CAS  Google Scholar 

  41. Kirsh, Yu.E., Kovner, V.Ya., Kokorin, A.I., Zamaraev, K.I., Chernyak, V.Ya., and Kabanov, V.A., Eur. Polym. J., 1974, vol. 10, no. 8, p. 671. https://doi.org/10.1016/0014-3057(74)90178-5

    Article  CAS  Google Scholar 

  42. Pilbrow, J.R., Transition Ion Electron Paramagnetic Resonance, Oxford: Clarendon Press, 1990. https://doi.org/10.1002/bbpc.19910951036

  43. Peisach, J. and Blumberg, W.E., Arch. Biochem. Biophys., 1974, vol. 165, no. 2, p. 691. https://doi.org/10.1016/0003-9861(74)90298-7

    Article  CAS  PubMed  Google Scholar 

  44. Sakaguchi, U., Addison, A.W., J. Chem. Soc. Dalton Trans., 1979, no. 4, p. 600. https://doi.org/10.1039/DT9790000600

    Article  Google Scholar 

  45. Lewis, W.B., Alei, M.Jr., and Morgan, L.O., J. Chem. Phys., 1966, vol. 44, no. 6, p. 2409. https://doi.org/10.1063/1.1727057

    Article  Google Scholar 

  46. Beck, M. and Nagypál, I., Chemistry of Complex Equilibria, Budapest: Akadémiai Kiadó, 1990. https://doi.org/10.1002/prac.19913330133

Download references

Author information

Authors and Affiliations

  1. Kazan Federal University, A. Butlerov Institute of Chemistry, 420008, Kazan, Russia

    A. R. Gataulina, V. A. Prytkov, N. A. Ulakhovich & M. P. Kutyreva

  2. Centre de Recherche en Cancérologie de Marseille, Institut Paoli-Calmette, Aix-Marseille University, 13009, Marseille, France

    P. O. Sidorov

  3. E. K. Zavoisky Kazan Physical-Technical Institute of the Russian Academy of Sciences, 420029, Kazan, Russia

    S. V. Yurtaeva

  4. Kazan National Research Technological University, 420015, Kazan, Russia

    G. A. Kutyrev

Authors
  1. A. R. Gataulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. O. Sidorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Yurtaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Prytkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. A. Ulakhovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. A. Kutyrev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. P. Kutyreva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. R. Gataulina.

Ethics declarations

No conflict of interest was declared by the authors.

Additional information

To the 80th Anniversary of R.A. Cherkasov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gataulina, A.R., Sidorov, P.O., Yurtaeva, S.V. et al. Ionization and Complexing Properties of Hyperbranched Polyester Poly[3-(2-aminoethyl)amino)]propionate. Russ J Gen Chem 90, 425–433 (2020). https://doi.org/10.1134/S1070363220030159

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220030159

Keywords:

Search

Navigation