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Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes

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Abstract

Novel polydentate ligands on the basis of second- and third-generation hyperbranched polyesters containing terminal poly[3-(morpholin-4-yl)propionate] groups and their 6 : 1 and 13 : 1 polynuclear copper(II) complexes were synthesized. The degree of functionalization of the polyesters with morpholine increases in going from the second (56%) to third generation (68%). According to IR and electronic spectroscopy data, each coordination entity in the complexes is an isolated paramagnetic center of the formula CuN2O2Solv2 (Solv = H2O, DMSO).

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Authors and Affiliations

  1. Butlerov Institute of Chemistry, Kazan (Volga region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    A. R. Gataulina, E. M. Khasanova, A. S. Basalaev, N. A. Ulakhovich & M. P. Kutyreva

  2. Kazan National Research Technological University, Kazan, Tatarstan, Russia

    G. A. Kutyrev

  3. Zavoiskii Physical-Technical Institute, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    S. V. Yurtaeva

Authors
  1. A. R. Gataulina
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  2. E. M. Khasanova
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  3. A. S. Basalaev
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  4. N. A. Ulakhovich
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  5. G. A. Kutyrev
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  6. S. V. Yurtaeva
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  7. M. P. Kutyreva
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Correspondence to A. R. Gataulina.

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Dedicated to V. F. Mironov on His 60th Anniversary

Original Russian Text © A.R. Gataulina, E.M. Khasanova, A.S. Basalaev, N.A. Ulakhovich, G.A. Kutyrev, S.V. Yurtaeva, M.P. Kutyreva, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 9, pp. 1515–1525.

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Gataulina, A.R., Khasanova, E.M., Basalaev, A.S. et al. Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes. Russ J Gen Chem 87, 1995–2005 (2017). https://doi.org/10.1134/S1070363217090158

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